Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes

Marchenko A, Koidan H, Hurieva A, Merkulov A, Pinchuk A, Yurchenko A, Rozhenko AB, Jones PG, Thoennessen H, Kostyuk A (2011)
Tetrahedron 67(40): 7748-7758.

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Abstract
A synthesis of 3H-1,3-benzazaphospholes starting from C-phosphorylated P(III) arylformamidines has been developed. Electron-donating substituents were found to enhance markedly the rate of the cyclization, with substituents at the meta position having the greatest effect. A plausible mechanism of the cyclization was proposed based on DFT calculations. (C) 2011 Elsevier Ltd. All rights reserved.
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Marchenko A, Koidan H, Hurieva A, et al. Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes. Tetrahedron. 2011;67(40):7748-7758.
Marchenko, A., Koidan, H., Hurieva, A., Merkulov, A., Pinchuk, A., Yurchenko, A., Rozhenko, A. B., et al. (2011). Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes. Tetrahedron, 67(40), 7748-7758.
Marchenko, A., Koidan, H., Hurieva, A., Merkulov, A., Pinchuk, A., Yurchenko, A., Rozhenko, A. B., Jones, P. G., Thoennessen, H., and Kostyuk, A. (2011). Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes. Tetrahedron 67, 7748-7758.
Marchenko, A., et al., 2011. Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes. Tetrahedron, 67(40), p 7748-7758.
A. Marchenko, et al., “Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes”, Tetrahedron, vol. 67, 2011, pp. 7748-7758.
Marchenko, A., Koidan, H., Hurieva, A., Merkulov, A., Pinchuk, A., Yurchenko, A., Rozhenko, A.B., Jones, P.G., Thoennessen, H., Kostyuk, A.: Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes. Tetrahedron. 67, 7748-7758 (2011).
Marchenko, Anatolyi, Koidan, Heorgii, Hurieva, Anastasiya, Merkulov, Anatolyi, Pinchuk, Aleksandr, Yurchenko, Aleksandr, Rozhenko, Alexander B., Jones, Peter G., Thoennessen, Holger, and Kostyuk, Aleksandr. “Cyclization of C-phosphorylated (P(III)) arylformamidines to 3H-1,3-benzazaphospholes”. Tetrahedron 67.40 (2011): 7748-7758.
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