CHIRAL CALIXARENES DERIVED FROM RESORCINOL

IWANEK W, Mattay J (1995)
Liebigs Annalen (8): 1463-1466.

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Abstract
A new type of chiral resorc[4]arene is described. The formation of both enantiomers of 5 is controlled by the chirality of the amines used in the Mannich reaction leading to the 1,3-oxazine ring anellated to the resorcarene moiety. At -50 degrees C ee increases up to 90 %. Both enantiomers can be easily purified to >98% ee by recrystallization. The structures were proved by standard methods including X-ray analysis.
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IWANEK W, Mattay J. CHIRAL CALIXARENES DERIVED FROM RESORCINOL. Liebigs Annalen. 1995;(8):1463-1466.
IWANEK, W., & Mattay, J. (1995). CHIRAL CALIXARENES DERIVED FROM RESORCINOL. Liebigs Annalen(8), 1463-1466.
IWANEK, W., and Mattay, J. (1995). CHIRAL CALIXARENES DERIVED FROM RESORCINOL. Liebigs Annalen, 1463-1466.
IWANEK, W., & Mattay, J., 1995. CHIRAL CALIXARENES DERIVED FROM RESORCINOL. Liebigs Annalen, (8), p 1463-1466.
W. IWANEK and J. Mattay, “CHIRAL CALIXARENES DERIVED FROM RESORCINOL”, Liebigs Annalen, 1995, pp. 1463-1466.
IWANEK, W., Mattay, J.: CHIRAL CALIXARENES DERIVED FROM RESORCINOL. Liebigs Annalen. 1463-1466 (1995).
IWANEK, W, and Mattay, Jochen. “CHIRAL CALIXARENES DERIVED FROM RESORCINOL”. Liebigs Annalen 8 (1995): 1463-1466.
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