[3+2] cycloadditions of aziridines mechanistical studies

Gaebert C, Mattay J (1996)
JOURNAL OF INFORMATION RECORDING 23(1-2): 3-6.

Journal Article | Published | English

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Abstract
The reaction of 1-butyl-2-phenyl aziridine with dimethyl acetylenedicarboxylate under PET conditions yields four products, two isomeric pyrrolidines and the corresponding pyrroles as oxidation products from the pyrrolidines. The reaction of the aziridine with dimethyl maleate and dimethyl fumarate respectively under PET conditions yields pyrroles with retained stereochemistry of the dipolarophiles. The addition of acrylonitrile to 1-butyl-trans-2,3-diphenyl aziridine under PET conditions leads to all four possible isomeric pyrrolidines whereas under direct photolysis only two pyrrolidines are formed. Based on these experimental data the mechanism involving a radical cation will be discussed.
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Gaebert C, Mattay J. [3+2] cycloadditions of aziridines mechanistical studies. JOURNAL OF INFORMATION RECORDING. 1996;23(1-2):3-6.
Gaebert, C., & Mattay, J. (1996). [3+2] cycloadditions of aziridines mechanistical studies. JOURNAL OF INFORMATION RECORDING, 23(1-2), 3-6.
Gaebert, C., and Mattay, J. (1996). [3+2] cycloadditions of aziridines mechanistical studies. JOURNAL OF INFORMATION RECORDING 23, 3-6.
Gaebert, C., & Mattay, J., 1996. [3+2] cycloadditions of aziridines mechanistical studies. JOURNAL OF INFORMATION RECORDING, 23(1-2), p 3-6.
C. Gaebert and J. Mattay, “[3+2] cycloadditions of aziridines mechanistical studies”, JOURNAL OF INFORMATION RECORDING, vol. 23, 1996, pp. 3-6.
Gaebert, C., Mattay, J.: [3+2] cycloadditions of aziridines mechanistical studies. JOURNAL OF INFORMATION RECORDING. 23, 3-6 (1996).
Gaebert, C, and Mattay, Jochen. “[3+2] cycloadditions of aziridines mechanistical studies”. JOURNAL OF INFORMATION RECORDING 23.1-2 (1996): 3-6.
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