Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene

Ramm M, Luger P, Strumpel M, Beurskens G, Averdung J, Mattay J (1998)
Zeitschrift für Kristallographie 213(1): 69-74.

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Abstract
The crystal structure of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2',3':1,2]- [60]fullerene was determined. The solution of the structure failed by direct methods, but succeeded by means of the program system DIRDIF-96. The asymmetric unit contains two fullerene molecules and one benzene molecule. The [1 + 2] cycloaddition leads to the formation of elongated bonds between the bridged C atoms. The average values of the [5, 6] and [6, 6] bond lengths in the C-60 spheres [1.448(6) Angstrom and 1.385(6) Angstrom] are close to those determined by electron diffraction [1.458(6) Angstrom and 1.40(1) Angstrom]. Due to the binding of the aziridino addend, the fullerene cage be comes slightly distorted relative to a free C-60 The bridged atoms 'stand out' of the C-60 surface by approximately 0.2 Angstrom. The shortest stacking distance for the fullerene spheres is the a cell translation. We can consider the parallel stacks, formed by the two independent molecules, as a layer that contains also most of the substituents atoms.
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Ramm M, Luger P, Strumpel M, Beurskens G, Averdung J, Mattay J. Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene. Zeitschrift für Kristallographie. 1998;213(1):69-74.
Ramm, M., Luger, P., Strumpel, M., Beurskens, G., Averdung, J., & Mattay, J. (1998). Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene. Zeitschrift für Kristallographie, 213(1), 69-74.
Ramm, M., Luger, P., Strumpel, M., Beurskens, G., Averdung, J., and Mattay, J. (1998). Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene. Zeitschrift für Kristallographie 213, 69-74.
Ramm, M., et al., 1998. Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene. Zeitschrift für Kristallographie, 213(1), p 69-74.
M. Ramm, et al., “Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene”, Zeitschrift für Kristallographie, vol. 213, 1998, pp. 69-74.
Ramm, M., Luger, P., Strumpel, M., Beurskens, G., Averdung, J., Mattay, J.: Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene. Zeitschrift für Kristallographie. 213, 69-74 (1998).
Ramm, M, Luger, P, Strumpel, M, Beurskens, G, Averdung, J, and Mattay, Jochen. “Crystal structure of a benzene solvate of N-(4-methoxycarbonylphenyl)oxycarbonylaziridino-[2 ',3 ': 1,2]-[60]fullerene”. Zeitschrift für Kristallographie 213.1 (1998): 69-74.
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