Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains

Glaser T, Heidemeier M, Hahn FE, Pape T, Lugger T (2003)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 58(6): 505-510.

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Abstract
The reaction of Cu(ClO4)(2).6H(2)O, imidazole (ImH), and ethylenediamine (en) in a 1: 2: 1 ratio afforded in high yield dark-blue single-crystals of [(en)Cu-II(ImH)(2)](ClO4)(2), 1, which can be used after deprotonation as a building block for heterometallic ferrimagnetic chains. The structural and electronic properties of 1 were examined by X-ray crystallography, FTIR, ESI-MS, electrochemistry, UV/vis/NIR, EPR, and magnetic susceptibility measurements. The structure of 1 exhibits intermolecular pi-pi interactions and hydrogen bonds but the magnetic data exclude the presence of intermolecular exchange interactions.
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Glaser T, Heidemeier M, Hahn FE, Pape T, Lugger T. Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2003;58(6):505-510.
Glaser, T., Heidemeier, M., Hahn, F. E., Pape, T., & Lugger, T. (2003). Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 58(6), 505-510.
Glaser, T., Heidemeier, M., Hahn, F. E., Pape, T., and Lugger, T. (2003). Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 58, 505-510.
Glaser, T., et al., 2003. Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 58(6), p 505-510.
T. Glaser, et al., “Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 58, 2003, pp. 505-510.
Glaser, T., Heidemeier, M., Hahn, F.E., Pape, T., Lugger, T.: Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 58, 505-510 (2003).
Glaser, Thorsten, Heidemeier, M, Hahn, FE, Pape, T, and Lugger, T. “Synthesis, characterization, crystal structure and magnetic properties of [(en)Cu-II(ImH)(2)](ClO4)(2) (en = ethylenediamine, ImH = imidazole): A metalloligand as a building block for heterometal chains”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 58.6 (2003): 505-510.
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