Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water

Schäffer C, Todea AM, Bögge H, Petina OA, Rehder D, Haupt ETK, Müller A (2011)
Chemistry 17(35): 9634-9639.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The investigation of hydrophobic interactions under confined conditions is of tremendous interdisciplinary interest. It is shown that based on porous capsules of the type {(pentagon)}(12){(linker)}(30) {(Mo)Mo(5)}(12){Mo(2)(ligand)}(30), which exhibit different hydrophobic interiors-achieved by coordinating related ligands to the internal sites of the 30 {Mo(2)} type linkers-there is the option to study systematically interactions with different uptaken/encapsulated hydrophobic molecules like long-chain alcohols as well as to prove the important correlation between the sizes of the related hydrophobic cavities and the option of water encapsulations. The measurements of 1D- and 2D-NMR spectra (e. g. ROESY, NOESY and HSQC) allowed the study of the interactions especially between encapsulated n-hexanol molecules and the hydrophobic interior formed by propionate ligands present in a new synthesized capsule. Future detailed studies will focus on interactions of a variety of hydrophobic species with different deliberately constructed hydrophobic capsule interiors.
Erscheinungsjahr
Zeitschriftentitel
Chemistry
Band
17
Zeitschriftennummer
35
Seite
9634-9639
ISSN
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Schäffer C, Todea AM, Bögge H, et al. Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water. Chemistry. 2011;17(35):9634-9639.
Schäffer, C., Todea, A. M., Bögge, H., Petina, O. A., Rehder, D., Haupt, E. T. K., & Müller, A. (2011). Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water. Chemistry, 17(35), 9634-9639. doi:10.1002/chem.201101454
Schäffer, C., Todea, A. M., Bögge, H., Petina, O. A., Rehder, D., Haupt, E. T. K., and Müller, A. (2011). Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water. Chemistry 17, 9634-9639.
Schäffer, C., et al., 2011. Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water. Chemistry, 17(35), p 9634-9639.
C. Schäffer, et al., “Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water”, Chemistry, vol. 17, 2011, pp. 9634-9639.
Schäffer, C., Todea, A.M., Bögge, H., Petina, O.A., Rehder, D., Haupt, E.T.K., Müller, A.: Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water. Chemistry. 17, 9634-9639 (2011).
Schäffer, Christian, Todea, Ana Maria, Bögge, Hartmut, Petina, Olga A., Rehder, Dieter, Haupt, Erhard T. K., and Müller, Achim. “Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water”. Chemistry 17.35 (2011): 9634-9639.

10 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Anions coordinating anions: analysis of the interaction between anionic Keplerate nanocapsules and their anionic ligands.
Melgar D, Bandeira NA, Bonet Avalos J, Bo C., Phys Chem Chem Phys 19(7), 2017
PMID: 28155941
The Uptake and Assembly of Alkanes within a Porous Nanocapsule in Water: New Information about Hydrophobic Confinement.
Kopilevich S, Gottlieb H, Keinan-Adamsky K, Müller A, Weinstock IA., Angew Chem Int Ed Engl 55(14), 2016
PMID: 26880403
Densely Packed Hydrophobic Clustering: Encapsulated Valerates Form a High-Temperature-Stable {Mo132 } Capsule System.
Garai S, Bögge H, Merca A, Petina OA, Grego A, Gouzerh P, Haupt ET, Weinstock IA, Müller A., Angew Chem Int Ed Engl 55(23), 2016
PMID: 27140207
Selenate as a novel ligand for keplerate chemistry. New {W72Mo60} keplerates with selenates inside the cavity.
Korenev VS, Abramov PA, Vicent C, Zhdanov AA, Tsygankova AR, Sokolov MN, Fedin VP., Dalton Trans 44(19), 2015
PMID: 25865040
Water repellency in hydrophobic nanocapsules--molecular view on dewetting.
Müller A, Garai S, Schäffer C, Merca A, Bögge H, Al-Karawi AJ, Prasad TK., Chemistry 20(22), 2014
PMID: 24782303
Achim Müller. Interview by Guido Clever.
Müller A., Angew Chem Int Ed Engl 52(3), 2013
PMID: 23283763
Stepwise-resolved thermodynamics of hydrophobic self-assembly.
Grego A, Müller A, Weinstock IA., Angew Chem Int Ed Engl 52(32), 2013
PMID: 23765614
Softening of pore and interior properties of a metal-oxide-based capsule: substituting 60 oxide by 60 sulfide ligands.
Schäffer C, Todea AM, Bögge H, Cadot E, Gouzerh P, Kopilevich S, Weinstock IA, Müller A., Angew Chem Int Ed Engl 50(51), 2011
PMID: 22034074

65 References

Daten bereitgestellt von Europe PubMed Central.


AUTHOR UNKNOWN, 0

Kauzmann, Adv. Prot. Chem. 14(), 1959
How protein chemists learned about the hydrophobic factor.
Tanford C., Protein Sci. 6(6), 1997
PMID: 9194199

Tanford, 1980
The hydrophobic effect and the organization of living matter.
Tanford C., Science 200(4345), 1978
PMID: 653353

Wiggins, Physica A 238(), 1997

Nelson, 2005

Alberts, 2002
Interfaces and the driving force of hydrophobic assembly.
Chandler D., Nature 437(7059), 2005
PMID: 16193038
Water in cavity-ligand recognition.
Baron R, Setny P, McCammon JA., J. Am. Chem. Soc. 132(34), 2010
PMID: 20695475

AUTHOR UNKNOWN, 0

Cronin, 2004
Towards polyoxometalate-integrated nanosystems.
Long DL, Cronin L., Chemistry 12(14), 2006
PMID: 16416497

Cronin, Angew. Chem. 118(), 2006
Inorganic molecular capsules: from structure to function.
Cronin L., Angew. Chem. Int. Ed. Engl. 45(22), 2006
PMID: 16683287
Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science.
Proust A, Thouvenot R, Gouzerh P., Chem. Commun. (Camb.) (16), 2008
PMID: 18401495

Gouzerh, Actual. Chim. 298(), 2006

Pope, 2004

Pope, 2005

AUTHOR UNKNOWN, 0

Müller, Coord. Chem. Rev. 245(), 2003

Müller, 2004
Molecular behavior in small spaces.
Rebek J Jr., Acc. Chem. Res. 42(10), 2009
PMID: 19603810

AUTHOR UNKNOWN, 0

Müller, Nature 447(), 2007

Müller, Coord. Chem. Rev. 222(), 2001

AUTHOR UNKNOWN, 0
Water in nonpolar confinement: from nanotubes to proteins and beyond.
Rasaiah JC, Garde S, Hummer G., Annu Rev Phys Chem 59(), 2008
PMID: 18092942
Water, water everywhere--except where it matters?
Homans SW., Drug Discov. Today 12(13-14), 2007
PMID: 17631247
Disordered water within a hydrophobic protein cavity visualized by x-ray crystallography.
Yu B, Blaber M, Gronenborn AM, Clore GM, Caspar DL., Proc. Natl. Acad. Sci. U.S.A. 96(1), 1999
PMID: 9874779

AUTHOR UNKNOWN, 0

Müller, J. Mater. Chem. 15(), 2005
Countercation transport modeled by porous spherical molybdenum oxide based nanocapsules.
Rehder D, Haupt ET, Bogge H, Muller A., Chem Asian J 1(1-2), 2006
PMID: 17441040

AUTHOR UNKNOWN, 0

Petina, Angew. Chem. 123(), 2011
Guests on different internal capsule sites exchange with each other and with the outside.
Petina O, Rehder D, Haupt ET, Grego A, Weinstock IA, Merca A, Bogge H, Szakacs J, Muller A., Angew. Chem. Int. Ed. Engl. 50(2), 2011
PMID: 21132826
Flexible pores of a metal oxide-based capsule permit entry of comparatively larger organic guests.
Ziv A, Grego A, Kopilevich S, Zeiri L, Miro P, Bo C, Muller A, Weinstock IA., J. Am. Chem. Soc. 131(18), 2009
PMID: 19290673

AUTHOR UNKNOWN, 0

AUTHOR UNKNOWN, 1990

Christen, 1992

AUTHOR UNKNOWN, 0

Müller, Inorg. Synth. 34(), 2004

Müller, Angew. Chem. 110(), 1998

AUTHOR UNKNOWN, Angew. Chem. Int. Ed. 37(), 1998

Schäffer, Angew. Chem. 121(), 2009
Unprecedented and differently applicable pentagonal units in a dynamic library: a keplerate of the type {(W)W5}12{Mo2}30.
Schaffer C, Merca A, Bogge H, Todea AM, Kistler ML, Liu T, Thouvenot R, Gouzerh P, Muller A., Angew. Chem. Int. Ed. Engl. 48(1), 2009
PMID: 19035609

Schäffer, Angew. Chem. 121(), 2009
A spherical 24 butyrate aggregate with a hydrophobic cavity in a capsule with flexible pores: confinement effects and uptake-release equilibria at elevated temperatures.
Schaffer C, Bogge H, Merca A, Weinstock IA, Rehder D, Haupt ET, Muller A., Angew. Chem. Int. Ed. Engl. 48(43), 2009
PMID: 19774583
Gated and differently functionalized (new) porous capsules direct encapsulates' structures: higher and lower density water.
Mitra T, Miro P, Tomsa AR, Merca A, Bogge H, Avalos JB, Poblet JM, Bo C, Muller A., Chemistry 15(8), 2009
PMID: 19130528

AUTHOR UNKNOWN, 0
Observation of a dewetting transition in the collapse of the melittin tetramer.
Liu P, Huang X, Zhou R, Berne BJ., Nature 437(7055), 2005
PMID: 16136146
Hydrophobicity of protein surfaces: Separating geometry from chemistry.
Giovambattista N, Lopez CF, Rossky PJ, Debenedetti PG., Proc. Natl. Acad. Sci. U.S.A. 105(7), 2008
PMID: 18268339

AUTHOR UNKNOWN, 0
Dewetting-controlled binding of ligands to hydrophobic pockets.
Setny P, Wang Z, Cheng LT, Li B, McCammon JA, Dzubiella J., Phys. Rev. Lett. 103(18), 2009
PMID: 19905832
Water at biomolecular binding interfaces.
Li Z, Lazaridis T., Phys Chem Chem Phys 9(5), 2006
PMID: 17242738
Structure validation in chemical crystallography.
Spek AL., Acta Crystallogr. D Biol. Crystallogr. 65(Pt 2), 2009
PMID: 19171970

Jacobsen, 2007
Discovering high-affinity ligands for proteins: SAR by NMR.
Shuker SB, Hajduk PJ, Meadows RP, Fesik SW., Science 274(5292), 1996
PMID: 8929414

AUTHOR UNKNOWN, 0

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