Polymeric materials: patterned polymer carpets

Amin I, Steenackers M, Zhang N, Schubel R, Beyer A, Gölzhäuser A, Jordan R (2011)
Small 7(5).

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Abstract
For the development of polymer carpets as active devices for micro- and nanotechnology, a control of the polymer carpet morphology and especially control of the stimulus responsive polymer brush is needed. Here, we report on the first example for the fabrication of patterned polymer carpets. On a two-dimensional framework of fully crosslinked and chemically patterned nanosheets, polymer brushes of styrene and 4-vinyl pyridine were grafted by self-initiated surface photopolymerization and photografting (SIPGP). It was found that polymer grafting by SIPGP occurred over the entire nanosheets but with a preferred grafting on the amino functionalized nanosheet areas. This results in continuous polymer carpets with an intact nanosheet framework but with amplification of the chemical patterning into a three dimensional topography of the grafted polymer brush. In the case of negative patterned nanosheets, the patterned carpet could be prepared as freestanding ultrathin membranes. Furthermore, swelling experiments with poly(4-vinyl pyridine) carpets showed that the patterns induces a directional buckling of the flexible polymer carpet. This may open the possibility of the development of micro- or nanoactuator devices with anisotropic responds upon environmental changes. Copyright 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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Amin I, Steenackers M, Zhang N, et al. Polymeric materials: patterned polymer carpets. Small. 2011;7(5).
Amin, I., Steenackers, M., Zhang, N., Schubel, R., Beyer, A., Gölzhäuser, A., & Jordan, R. (2011). Polymeric materials: patterned polymer carpets. Small, 7(5).
Amin, I., Steenackers, M., Zhang, N., Schubel, R., Beyer, A., Gölzhäuser, A., and Jordan, R. (2011). Polymeric materials: patterned polymer carpets. Small 7.
Amin, I., et al., 2011. Polymeric materials: patterned polymer carpets. Small, 7(5).
I. Amin, et al., “Polymeric materials: patterned polymer carpets”, Small, vol. 7, 2011.
Amin, I., Steenackers, M., Zhang, N., Schubel, R., Beyer, A., Gölzhäuser, A., Jordan, R.: Polymeric materials: patterned polymer carpets. Small. 7, (2011).
Amin, Ihsan, Steenackers, Marin, Zhang, Ning, Schubel, Rene, Beyer, André, Gölzhäuser, Armin, and Jordan, Rainer. “Polymeric materials: patterned polymer carpets”. Small 7.5 (2011).
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4 Citations in Europe PMC

Data provided by Europe PubMed Central.

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A microcontact printing induced supramolecular self-assembled photoactive surface for patterning polymer brushes.
Xiao P, Gu J, Chen J, Han D, Zhang J, Cao H, Xing R, Han Y, Wang W, Chen T., Chem. Commun. (Camb.) 49(95), 2013
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35 References

Data provided by Europe PubMed Central.

Two-Dimensional Polymers: Just a Dream of Synthetic Chemists?
Sakamoto, Angewandte Chemie International Edition 48(6), 2009
Engineered Polymer Brushes by Carbon Templating
Steenackers, Advanced Materials 21(28), 2009
Formation of Hierarchically Structured Thin Films
Wang, Advanced Functional Materials 19(14), 2009
Bottle-Brush Brushes: Cylindrical Molecular Brushes of Poly(2-oxazoline) on Glassy Carbon
Zhang, Macromolecules 42(14), 2009
Structured Polymer Brushes on Silicon Carbide
Steenackers, Chemistry of Materials 22(1), 2010
Blood compatibility of photografted hydrogel coatings.
Faxalv L, Ekblad T, Liedberg B, Lindahl TL., Acta Biomater 6(7), 2010
PMID: 20045090
Microstructured poly(2-oxazoline) bottle-brush brushes on nanocrystalline diamond.
Hutter NA, Reitinger A, Zhang N, Steenackers M, Williams OA, Garrido JA, Jordan R., Phys Chem Chem Phys 12(17), 2010
PMID: 20407707
Swelling-induced folding in confined nanoscale responsive polymer gels.
Singamaneni S, McConney ME, Tsukruk VV., ACS Nano 4(4), 2010
PMID: 20232813
Controlled Bending of Microscale Au−Polyelectrolyte Brush Bilayers
Kelby, Macromolecules 43(12), 2010

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