Polymeric materials: patterned polymer carpets

Amin I, Steenackers M, Zhang N, Schubel R, Beyer A, Gölzhäuser A, Jordan R (2011)
Small 7(5).

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
For the development of polymer carpets as active devices for micro- and nanotechnology, a control of the polymer carpet morphology and especially control of the stimulus responsive polymer brush is needed. Here, we report on the first example for the fabrication of patterned polymer carpets. On a two-dimensional framework of fully crosslinked and chemically patterned nanosheets, polymer brushes of styrene and 4-vinyl pyridine were grafted by self-initiated surface photopolymerization and photografting (SIPGP). It was found that polymer grafting by SIPGP occurred over the entire nanosheets but with a preferred grafting on the amino functionalized nanosheet areas. This results in continuous polymer carpets with an intact nanosheet framework but with amplification of the chemical patterning into a three dimensional topography of the grafted polymer brush. In the case of negative patterned nanosheets, the patterned carpet could be prepared as freestanding ultrathin membranes. Furthermore, swelling experiments with poly(4-vinyl pyridine) carpets showed that the patterns induces a directional buckling of the flexible polymer carpet. This may open the possibility of the development of micro- or nanoactuator devices with anisotropic responds upon environmental changes. Copyright 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.


Amin I, Steenackers M, Zhang N, et al. Polymeric materials: patterned polymer carpets. Small. 2011;7(5).
Amin, I., Steenackers, M., Zhang, N., Schubel, R., Beyer, A., Gölzhäuser, A., & Jordan, R. (2011). Polymeric materials: patterned polymer carpets. Small, 7(5). doi:10.1002/smll.201190012
Amin, I., Steenackers, M., Zhang, N., Schubel, R., Beyer, A., Gölzhäuser, A., and Jordan, R. (2011). Polymeric materials: patterned polymer carpets. Small 7.
Amin, I., et al., 2011. Polymeric materials: patterned polymer carpets. Small, 7(5).
I. Amin, et al., “Polymeric materials: patterned polymer carpets”, Small, vol. 7, 2011.
Amin, I., Steenackers, M., Zhang, N., Schubel, R., Beyer, A., Gölzhäuser, A., Jordan, R.: Polymeric materials: patterned polymer carpets. Small. 7, (2011).
Amin, Ihsan, Steenackers, Marin, Zhang, Ning, Schubel, Rene, Beyer, André, Gölzhäuser, Armin, and Jordan, Rainer. “Polymeric materials: patterned polymer carpets”. Small 7.5 (2011).

8 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Nanopatterned polymer brushes: conformation, fabrication and applications.
Yu Q, Ista LK, Gu R, Zauscher S, López GP., Nanoscale 8(2), 2016
PMID: 26648412
Mussel-Inspired Polymer Carpets: Direct Photografting of Polymer Brushes on Polydopamine Nanosheets for Controlled Cell Adhesion.
Hafner D, Ziegler L, Ichwan M, Zhang T, Schneider M, Schiffmann M, Thomas C, Hinrichs K, Jordan R, Amin I., Adv Mater 28(7), 2016
PMID: 26671880
One-Reactant Photografting of ATRP Initiators for Surface-Initiated Polymerization.
Styan KE, Easton CD, Weaver LG, Meagher L., Macromol Rapid Commun 37(13), 2016
PMID: 27145108
Carbon Nanomembranes.
Turchanin A, Gölzhäuser A., Adv Mater 28(29), 2016
PMID: 27281234
Amino-terminated biphenylthiol self-assembled monolayers as highly reactive molecular templates.
Meyerbroeker N, Waske P, Zharnikov M., J Chem Phys 142(10), 2015
PMID: 25770508
A microcontact printing induced supramolecular self-assembled photoactive surface for patterning polymer brushes.
Xiao P, Gu J, Chen J, Han D, Zhang J, Cao H, Xing R, Han Y, Wang W, Chen T., Chem Commun (Camb) 49(95), 2013
PMID: 24150764
Patterned polymer brushes.
Chen T, Amin I, Jordan R., Chem Soc Rev 41(8), 2012
PMID: 22234473
Tailored poly(2-oxazoline) polymer brushes to control protein adsorption and cell adhesion.
Zhang N, Pompe T, Amin I, Luxenhofer R, Werner C, Jordan R., Macromol Biosci 12(7), 2012
PMID: 22610725

35 References

Daten bereitgestellt von Europe PubMed Central.

Two-Dimensional Polymers: Just a Dream of Synthetic Chemists?
Sakamoto, Angewandte Chemie International Edition 48(6), 2009
Engineered Polymer Brushes by Carbon Templating
Steenackers, Advanced Materials 21(28), 2009
Formation of Hierarchically Structured Thin Films
Wang, Advanced Functional Materials 19(14), 2009
Bottle-Brush Brushes: Cylindrical Molecular Brushes of Poly(2-oxazoline) on Glassy Carbon
Zhang, Macromolecules 42(14), 2009
Structured Polymer Brushes on Silicon Carbide
Steenackers, Chemistry of Materials 22(1), 2010
Blood compatibility of photografted hydrogel coatings.
Faxalv L, Ekblad T, Liedberg B, Lindahl TL., Acta Biomater 6(7), 2010
PMID: 20045090
Microstructured poly(2-oxazoline) bottle-brush brushes on nanocrystalline diamond.
Hutter NA, Reitinger A, Zhang N, Steenackers M, Williams OA, Garrido JA, Jordan R., Phys Chem Chem Phys 12(17), 2010
PMID: 20407707
Swelling-induced folding in confined nanoscale responsive polymer gels.
Singamaneni S, McConney ME, Tsukruk VV., ACS Nano 4(4), 2010
PMID: 20232813
Controlled Bending of Microscale Au−Polyelectrolyte Brush Bilayers
Kelby, Macromolecules 43(12), 2010


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