Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy

Schröder T, Sahu S, Anselmetti D, Mattay J (2011)
Israel Journal of Chemistry 51(7): 725-742.

Journal Article | Published | English

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Abstract
Self-assembly by H-bonding and by metal-coordination of functionalized calix[4]arenes and cavitands to large supramolecular capsules is described. In addition, a new method of analyzing supramolecular recognition processes at the single molecule level is discussed. By measuring interaction forces in a hydrogen-bonded assembly using single-molecule force spectroscopy (SMFS), the dynamics of the self-assembly process can be evaluated. In the future, consequent application of this new technique will influence supramolecular design principles and the use of non-covalent interactions as construction elements in the field of nanotechnology.
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Schröder T, Sahu S, Anselmetti D, Mattay J. Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy. Israel Journal of Chemistry. 2011;51(7):725-742.
Schröder, T., Sahu, S., Anselmetti, D., & Mattay, J. (2011). Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy. Israel Journal of Chemistry, 51(7), 725-742.
Schröder, T., Sahu, S., Anselmetti, D., and Mattay, J. (2011). Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy. Israel Journal of Chemistry 51, 725-742.
Schröder, T., et al., 2011. Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy. Israel Journal of Chemistry, 51(7), p 725-742.
T. Schröder, et al., “Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy”, Israel Journal of Chemistry, vol. 51, 2011, pp. 725-742.
Schröder, T., Sahu, S., Anselmetti, D., Mattay, J.: Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy. Israel Journal of Chemistry. 51, 725-742 (2011).
Schröder, Tobias, Sahu, Satya, Anselmetti, Dario, and Mattay, Jochen. “Supramolecular Capsules Derived from Resorcin[4]arenes by H-Bonding and Metal Coordination: Synthesis, Characterization and Single-Molecule Force Spectroscopy”. Israel Journal of Chemistry 51.7 (2011): 725-742.
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