Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes

Mason K, Chang J, Garlatti E, Prescimone A, Yoshii S, Nojiri H, Schnack J, Tasker PA, Carretta S, Brechin EK (2011)
Chemical Communications 47(21): 6018-6020.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The use of "double-headed" phenolic oximes produces a trigonal antiprismatic [Fe-3(III)](2) cluster with an "internal cavity" filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.
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Zeitschriftentitel
Chemical Communications
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47
Zeitschriftennummer
21
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6018-6020
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Mason K, Chang J, Garlatti E, et al. Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes. Chemical Communications. 2011;47(21):6018-6020.
Mason, K., Chang, J., Garlatti, E., Prescimone, A., Yoshii, S., Nojiri, H., Schnack, J., et al. (2011). Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes. Chemical Communications, 47(21), 6018-6020. doi:10.1039/c1cc11146a
Mason, K., Chang, J., Garlatti, E., Prescimone, A., Yoshii, S., Nojiri, H., Schnack, J., Tasker, P. A., Carretta, S., and Brechin, E. K. (2011). Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes. Chemical Communications 47, 6018-6020.
Mason, K., et al., 2011. Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes. Chemical Communications, 47(21), p 6018-6020.
K. Mason, et al., “Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes”, Chemical Communications, vol. 47, 2011, pp. 6018-6020.
Mason, K., Chang, J., Garlatti, E., Prescimone, A., Yoshii, S., Nojiri, H., Schnack, J., Tasker, P.A., Carretta, S., Brechin, E.K.: Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes. Chemical Communications. 47, 6018-6020 (2011).
Mason, K., Chang, J., Garlatti, E., Prescimone, A., Yoshii, S., Nojiri, H., Schnack, Jürgen, Tasker, P. A., Carretta, S., and Brechin, E. K. “Linking [Fe-3(III)] triangles with "double-headed" phenolic oximes”. Chemical Communications 47.21 (2011): 6018-6020.

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The synthesis of three new Cu5, Cu8 and Cu12 clusters via the use of a semi-flexible aminotriazine-based bis-methylpyridine ligand.
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PMID: 28059407

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