Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study

Evenhuis CR, Manthe U (2011)
The Journal of Physical Chemistry A 115(23): 5992-6001.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The photodissociation of methyl iodide in the A band is studied by full-dimensional (9D) wave packet dynamics calculations using the multiconfigurational time-dependent Hartree approach. The potential energy surfaces employed are based on the diabatic potentials of Xie et al. [J. Phys. Chem. A 2000, 104, 1009] and the vertical excitation energy is taken from recent ab initio calculations [Alekseyev et al. J. Chem. Phys. 2007, 126, 234102]. The absorption spectrum calculated for exclusively parallel excitation agrees well with the experimental spectrum of the A band. The electronic population dynamics is found to be strongly dependent on the motion in the torsional coordinate related to the H-3-C-I bend, which presumably is an artifact of the diabatic model employed. The calculated fully product state-selected partial spectra can be interpreted based on the reflection principle and suggests strong coupling between the C-I stretching and the H-3-C-I bending motions during the dissociation process. The computed rotational and vibrational product distributions typically reproduce the trends seen in the experiment In agreement with experiment, a small but significant excitation of the total symmetric stretching and the asymmetric bending modes of the methyl fragment can be seen. In contrast, the umbrella mode of the methyl is found to be too highly excited in the calculated distributions.
Erscheinungsjahr
Zeitschriftentitel
The Journal of Physical Chemistry A
Band
115
Zeitschriftennummer
23
Seite
5992-6001
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Evenhuis CR, Manthe U. Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study. The Journal of Physical Chemistry A. 2011;115(23):5992-6001.
Evenhuis, C. R., & Manthe, U. (2011). Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study. The Journal of Physical Chemistry A, 115(23), 5992-6001. doi:10.1021/jp1103998
Evenhuis, C. R., and Manthe, U. (2011). Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study. The Journal of Physical Chemistry A 115, 5992-6001.
Evenhuis, C.R., & Manthe, U., 2011. Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study. The Journal of Physical Chemistry A, 115(23), p 5992-6001.
C.R. Evenhuis and U. Manthe, “Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study”, The Journal of Physical Chemistry A, vol. 115, 2011, pp. 5992-6001.
Evenhuis, C.R., Manthe, U.: Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study. The Journal of Physical Chemistry A. 115, 5992-6001 (2011).
Evenhuis, Christian R., and Manthe, Uwe. “Photodissociation of CH3I: A Full-Dimensional (9D) Quantum Dynamics Study”. The Journal of Physical Chemistry A 115.23 (2011): 5992-6001.

13 Zitationen in Europe PMC

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A velocity-map imaging study of methyl non-resonant multiphoton ionization from the photodissociation of CH3I in the A-band.
Poullain SM, Chicharro DV, Rubio-Lago L, García-Vela A, Bañares L., Philos Trans A Math Phys Eng Sci 375(2092), 2017
PMID: 28320907
Semiclassical Wigner theory of photodissociation in three dimensions: Shedding light on its basis.
Arbelo-González W, Bonnet L, García-Vela A., J Chem Phys 142(13), 2015
PMID: 25854232
New insights into the photodissociation of methyl iodide at 193 nm: stereodynamics and product branching ratios.
Marggi Poullain S, González MG, Samartzis PC, Kitsopoulos TN, Rubio-Lago L, Bañares L., Phys Chem Chem Phys 17(44), 2015
PMID: 26489797
New insights into the semiclassical Wigner treatment of photodissociation dynamics.
Arbelo-González W, Bonnet L, García-Vela A., Phys Chem Chem Phys 15(25), 2013
PMID: 23712618
A 4D wave packet study of the CH3I photodissociation in the A-band. Comparison with femtosecond velocity map imaging experiments.
García-Vela A, de Nalda R, Durá J, González-Vázquez J, Bañares L., J Chem Phys 135(15), 2011
PMID: 22029312

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