Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand

Hellmann B, Neumann B, Stammler H-G, Mitzel NW (2010)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 65(10): 1279-1283.

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Abstract
The three component reaction of LnCp(3), LnCp(2)Cl (Ln = Nd, Y) and N,N-bis[2-(pyrid-2-yl)ethyl]hydroxylamine [HON(C2H4-o-py)(2)] results in the formation of the [Nd(ON(C2H4-o-py)(2))(2)](+) [NdCp3Cl](-) salt in the case of neodymium and the [Y(ON(C2H4-o-py)(2))(2)](+)[YCp2Cl2](-) salt if yttrium is used in the synthesis. The N,N-bis[2-(pyrid-2-yl)ethyl]hydroxylaminato ligand is able to coordinate doubly to the metal atoms resulting in the formation of a cationic species. The compounds were characterised by X-ray diffraction experiments and additionally by CHN analyses in the case of the neodymium salt.
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Hellmann B, Neumann B, Stammler H-G, Mitzel NW. Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2010;65(10):1279-1283.
Hellmann, B., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2010). Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 65(10), 1279-1283.
Hellmann, B., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2010). Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 65, 1279-1283.
Hellmann, B., et al., 2010. Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 65(10), p 1279-1283.
B. Hellmann, et al., “Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 65, 2010, pp. 1279-1283.
Hellmann, B., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 65, 1279-1283 (2010).
Hellmann, Benjamin, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Molecular Neodymium and Yttrium Cations with the N,N-Bis[2-(pyrid-2-yl)ethyl]hydroxylaminato Ligand”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 65.10 (2010): 1279-1283.
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