PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES

Mitzel NW, SCHIER A, BERUDA H, SCHMIDBAUR H (1992)
CHEMISCHE BERICHTE-RECUEIL 125(5): 1053-1059.

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Abstract
The synthesis of 1,3-diphenyldisiloxane (1) by hydrolysis of chloro(phenyl)silane is optimized, 1,3-diphenyldisilthiane (2) is made available by the reaction of H2S with PhH2SiCl and triethylamine. 1,3-Diphenyldisilselenane (3) is prepared from K2Se and PhH2SiBr. Selective ammonolysis of PhH2SiBr leads either to bis(phenylsilyl)amine (4) or to tris(phenylsilyl)amine (5). (Phenylsilyl)bis(trimethylsilyl)amine (6) is prepared by the reaction of 1,1,1,3,3,3-hexamethyldisilazane with chloro(phenyl) silane and triethylamine. According to a crystal structure determination the molecule of 6 features a planar Si3N skeleton. Phenylsilylated phosphonium methylides are available by two synthetic pathways: Transsilylation of phosphonium (trimethylsilyl)methylides and direct silylation of unsubstituted phosphonium methylides R3P=CH2. The structure of the molecule Me3P=C(SiH2Ph)2 (11) in the crystal also exhibits a virtually planar PCSi2 skeleton, isoelectronic with Si3N.
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Mitzel NW, SCHIER A, BERUDA H, SCHMIDBAUR H. PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES. CHEMISCHE BERICHTE-RECUEIL. 1992;125(5):1053-1059.
Mitzel, N. W., SCHIER, A., BERUDA, H., & SCHMIDBAUR, H. (1992). PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES. CHEMISCHE BERICHTE-RECUEIL, 125(5), 1053-1059.
Mitzel, N. W., SCHIER, A., BERUDA, H., and SCHMIDBAUR, H. (1992). PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES. CHEMISCHE BERICHTE-RECUEIL 125, 1053-1059.
Mitzel, N.W., et al., 1992. PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES. CHEMISCHE BERICHTE-RECUEIL, 125(5), p 1053-1059.
N.W. Mitzel, et al., “PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES”, CHEMISCHE BERICHTE-RECUEIL, vol. 125, 1992, pp. 1053-1059.
Mitzel, N.W., SCHIER, A., BERUDA, H., SCHMIDBAUR, H.: PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES. CHEMISCHE BERICHTE-RECUEIL. 125, 1053-1059 (1992).
Mitzel, Norbert W., SCHIER, A, BERUDA, H, and SCHMIDBAUR, H. “PHENYLSILYL CHALCOGENIDES, (PHENYLSILYL)AMINES AND RELATED PHOSPHONIUM (PHENYLSILYL)METHYLIDES”. CHEMISCHE BERICHTE-RECUEIL 125.5 (1992): 1053-1059.
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