PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES

Mitzel NW, RIEDE J, SCHIER A, PAUL M, SCHMIDBAUR H (1993)
CHEMISCHE BERICHTE-RECUEIL 126(9): 2027-2032.

Journal Article | Published | English

No fulltext has been uploaded

Author
; ; ; ;
Abstract
The synthesis and characterization of two complete series of benzyl(phenylsilyl)amines (PhH2Si)x(PhH2C)3 - N, benzyl(p-tolylsilyl)amines (p-H3CC6H4H2Si)x(PhH2C)3-xN, and of bis-(p-tolylsilyl)amine are described. The compounds have been prepared from the corresponding amines and chlorosilanes with triethylamine as the auxiliary base. Bis(phenylsi-lyl)(trimethylsilyl)amine, (PhH2Si)2NSiMe3 (10), was obtained by the reaction of lithium bis(phenylsilyl)amide with chlorotrimethylsilane. Crystal structure analyses reveal that dibenzyl(p-tolylsilyl)amine (7) and 10 contain planar nitrogen atoms. Heteronuclear NMR spectra (H-1, C-13, N-15, and Si-29) have been measured for all compounds. The N-15 chemical shifts are shown to be sensitive to variations of the geometry at the nitrogen atom. The coupling constants (1J(NSi))-N-15-Si-29 show a linear correlation with the N-Si bond lengths.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Mitzel NW, RIEDE J, SCHIER A, PAUL M, SCHMIDBAUR H. PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES. CHEMISCHE BERICHTE-RECUEIL. 1993;126(9):2027-2032.
Mitzel, N. W., RIEDE, J., SCHIER, A., PAUL, M., & SCHMIDBAUR, H. (1993). PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES. CHEMISCHE BERICHTE-RECUEIL, 126(9), 2027-2032.
Mitzel, N. W., RIEDE, J., SCHIER, A., PAUL, M., and SCHMIDBAUR, H. (1993). PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES. CHEMISCHE BERICHTE-RECUEIL 126, 2027-2032.
Mitzel, N.W., et al., 1993. PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES. CHEMISCHE BERICHTE-RECUEIL, 126(9), p 2027-2032.
N.W. Mitzel, et al., “PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES”, CHEMISCHE BERICHTE-RECUEIL, vol. 126, 1993, pp. 2027-2032.
Mitzel, N.W., RIEDE, J., SCHIER, A., PAUL, M., SCHMIDBAUR, H.: PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES. CHEMISCHE BERICHTE-RECUEIL. 126, 2027-2032 (1993).
Mitzel, Norbert W., RIEDE, J, SCHIER, A, PAUL, M, and SCHMIDBAUR, H. “PREPARATIVE, SPECTROSCOPIC, AND STRUCTURAL STUDIES ON SOME NEW SILYLAMINES”. CHEMISCHE BERICHTE-RECUEIL 126.9 (1993): 2027-2032.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar