SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION

Mitzel NW, ANGERMAIER K, SCHMIDBAUR H (1994)
ORGANOMETALLICS 13(5): 1762-1766.

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Abstract
Five (arylsilyl)hydroxylamines (1-5) were prepared from the corresponding arylhalosilanes and alkylated hydroxylamines in the presence of triethylamine as an auxiliary base. The crystal structure of (p-tolH2Si)2NOMe (3) shows the Si2NO group to be clearly pyramidal, a unique feature in Si/N chemistry. The conformation of the Si2NOC skeleton is found to be the same as in alkylated hydroxylamines. The NMR spectra of all five elements present in the compounds (H-1, C-13, N-15, O-17, Si-29) have been measured and are discussed. In this context 1J((NSi)-N-15-Si-29) coupling constants were found to reflect the unusual nitrogen hybridization in the pyramidal configuration.
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Mitzel NW, ANGERMAIER K, SCHMIDBAUR H. SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION. ORGANOMETALLICS. 1994;13(5):1762-1766.
Mitzel, N. W., ANGERMAIER, K., & SCHMIDBAUR, H. (1994). SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION. ORGANOMETALLICS, 13(5), 1762-1766.
Mitzel, N. W., ANGERMAIER, K., and SCHMIDBAUR, H. (1994). SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION. ORGANOMETALLICS 13, 1762-1766.
Mitzel, N.W., ANGERMAIER, K., & SCHMIDBAUR, H., 1994. SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION. ORGANOMETALLICS, 13(5), p 1762-1766.
N.W. Mitzel, K. ANGERMAIER, and H. SCHMIDBAUR, “SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION”, ORGANOMETALLICS, vol. 13, 1994, pp. 1762-1766.
Mitzel, N.W., ANGERMAIER, K., SCHMIDBAUR, H.: SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION. ORGANOMETALLICS. 13, 1762-1766 (1994).
Mitzel, Norbert W., ANGERMAIER, K, and SCHMIDBAUR, H. “SILYLHYDROXYLAMINES - COMPOUNDS WITH UNUSUAL NITROGEN COORDINATION”. ORGANOMETALLICS 13.5 (1994): 1762-1766.
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