PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES

Mitzel NW, SCHMIDBAUR H (1994)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 620(6): 1087-1092.

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Abstract
(Hydridosilyl)hydroxylamines have been prepared from the corresponding chloro- and bromosilanes and alkylated hydroxylamines in the presence of an auxiliary base (NEt3, TMEDA). Dimethylsilyl groups were introduced in order to obtain open chain silylhydroxylamines, while alpha,omega-disilylalkane groups were employed for cyclic species. In mass spectral studies a nitrene extrusion was found to be one of the main fragmentation processes. N-15, O-17 (and H-1, C-13, Si-29) heteronuclear NMR studies were carried out for a larger series of silylated and alkylated hydroxylamines. The O-17 and N-15 chemical shifts are clearly distinguished from those of other compounds containing saturated nitrogen and oxygen centers. The one bond coupling constants 1J((NSi)-N-15-Si-29) indicate a pyramidal coordination of nitrogen in silylhydroxylamines.
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Mitzel NW, SCHMIDBAUR H. PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 1994;620(6):1087-1092.
Mitzel, N. W., & SCHMIDBAUR, H. (1994). PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 620(6), 1087-1092.
Mitzel, N. W., and SCHMIDBAUR, H. (1994). PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 620, 1087-1092.
Mitzel, N.W., & SCHMIDBAUR, H., 1994. PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 620(6), p 1087-1092.
N.W. Mitzel and H. SCHMIDBAUR, “PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 620, 1994, pp. 1087-1092.
Mitzel, N.W., SCHMIDBAUR, H.: PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 620, 1087-1092 (1994).
Mitzel, Norbert W., and SCHMIDBAUR, H. “PREPARATIVE AND SPECTROSCOPIC STUDIES ON VOLATILE SILYLHYDROXYLAMINES AND ALKYLHYDROXYLAMINES”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 620.6 (1994): 1087-1092.
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