Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units

Mitzel NW (1998)
CHEMISTRY-A EUROPEAN JOURNAL 4(4): 692-698.

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Abstract
Two simple silylhydrazines, H3SiMeNNMe2 and (H3Si)(2)NNMe2, have been prepared by the reaction of bromosilane with the corresponding NH-functional hydrazine in the presence of a base and the appropriate lithiated hydrazine. The intermolecular attractive interactions (beta-donor-acceptor interaction) between the silicon and beta-nitrogen atoms of H3SiMeNNMe2 and (H3Si)(2)NNMe2 has been demonstrated by low-temperature X-ray crystallography and ab initio calculations (MP2/6-311G). The contributions to the strength of this two-bond interaction are discussed in the light of a new series of calculations on RSiH2NR'NR2 " molecules (R=H, F; R'=H, Me, SiH3; R "=H, Me), which show electronegative substituents at the silicon acceptor center to exert the largest effect, while the electronic nature of the substituent at the P-nitrogen atom is also important. As the resulting structures cannot be described satisfactorily by either the VSEPR concept or Bartell's two-bond radius model, a two-bond interatomic attraction has to be taken into account in addition; this leads to an extension of the common models for empirical structure prediction.
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Mitzel NW. Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units. CHEMISTRY-A EUROPEAN JOURNAL. 1998;4(4):692-698.
Mitzel, N. W. (1998). Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units. CHEMISTRY-A EUROPEAN JOURNAL, 4(4), 692-698.
Mitzel, N. W. (1998). Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units. CHEMISTRY-A EUROPEAN JOURNAL 4, 692-698.
Mitzel, N.W., 1998. Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units. CHEMISTRY-A EUROPEAN JOURNAL, 4(4), p 692-698.
N.W. Mitzel, “Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units”, CHEMISTRY-A EUROPEAN JOURNAL, vol. 4, 1998, pp. 692-698.
Mitzel, N.W.: Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units. CHEMISTRY-A EUROPEAN JOURNAL. 4, 692-698 (1998).
Mitzel, Norbert W. “Simple silylhydrazines as models for Si-N beta-donor interactions in SiNN units”. CHEMISTRY-A EUROPEAN JOURNAL 4.4 (1998): 692-698.
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