Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid

Wilton-Ely JDET, Schier A, Mitzel NW, Schmidbaur H (2001)
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (7): 1058-1062.

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Abstract
Treatment of the gold(I) halide species AuLCl (where L=PMe3, PEt3, PPh3, PPh2(C5H4N-2) or SPPh3) and (AuCl)(2)(P-P) (where P-P=1,4-bis(diphenylphosphino)butane or 1,1'-bis(diphenylphosphino)ferrocene) with 4-sulfanylbenzoic acid (1 or 2 equivalents as required) in the presence of sodium methoxide provided the corresponding phosphine gold(I) thiolate complexes AuL(4-SC6H4CO2H) and [Au(4-SC6H4CO2H)](2)(P-P), respectively. Addition of two equivalents of the acid (in the presence of NaOMe) to [N(PPh3)(2)][AuCl2] yielded the dithiolate species [N(PPh3)(2)][Au(4-SC6H4CO2H)(2)]. A polyaurated product [(Ph3PAu)(2)(4-SC6H4CO2H)]BF4 was obtained on treating the acid with the oxonium complex [(Ph3PAu)(3)O]BF4. The species AuL(4-SC6H4CO2H) (L=PEt3, PPh3 or PPh2(C5H4N-2)) have been investigated crystallographically and reveal diverse structures incorporating aurophilic contacts, Au . . .S interactions and hydrogen bonding.
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Wilton-Ely JDET, Schier A, Mitzel NW, Schmidbaur H. Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS. 2001;(7):1058-1062.
Wilton-Ely, J. D. E. T., Schier, A., Mitzel, N. W., & Schmidbaur, H. (2001). Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS(7), 1058-1062.
Wilton-Ely, J. D. E. T., Schier, A., Mitzel, N. W., and Schmidbaur, H. (2001). Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1058-1062.
Wilton-Ely, J.D.E.T., et al., 2001. Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (7), p 1058-1062.
J.D.E.T. Wilton-Ely, et al., “Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid”, JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, pp. 1058-1062.
Wilton-Ely, J.D.E.T., Schier, A., Mitzel, N.W., Schmidbaur, H.: Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS. 1058-1062 (2001).
Wilton-Ely, JDET, Schier, A, Mitzel, Norbert W., and Schmidbaur, H. “Structural diversity in gold(I) complexes of 4-sulfanylbenzoic acid”. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS 7 (2001): 1058-1062.
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