Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex

Rabe GW, Mitzel NW (2001)
INORGANICA CHIMICA ACTA 316(1-2): 132-134.

Journal Article | Published | English

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The synthesis and X-ray crystal structure determination of a novel metal-terphenyl derivative, namely DmpAuPPh(3) (1). is reported (Dmp = 2,6-dimesitylphenyl). Complex 1 is synthesized by the reaction of one equivalent of DmDLi with one equivalent of Ph3PAuCl in tetrahydrofuran at room temperature in 70% yield. The molecular structure of monomeric 1 features a two-coordinate gold atom with an essentially linear arrangement of the two ligands with an interligand angle of 174.21(8)degrees as well as a slightly tilted terphenyl moiety. (C) 2001 Elsevier Science B.V. All rights reserved.
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Rabe GW, Mitzel NW. Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex. INORGANICA CHIMICA ACTA. 2001;316(1-2):132-134.
Rabe, G. W., & Mitzel, N. W. (2001). Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex. INORGANICA CHIMICA ACTA, 316(1-2), 132-134.
Rabe, G. W., and Mitzel, N. W. (2001). Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex. INORGANICA CHIMICA ACTA 316, 132-134.
Rabe, G.W., & Mitzel, N.W., 2001. Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex. INORGANICA CHIMICA ACTA, 316(1-2), p 132-134.
G.W. Rabe and N.W. Mitzel, “Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex”, INORGANICA CHIMICA ACTA, vol. 316, 2001, pp. 132-134.
Rabe, G.W., Mitzel, N.W.: Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex. INORGANICA CHIMICA ACTA. 316, 132-134 (2001).
Rabe, GW, and Mitzel, Norbert W. “Synthesis and X-ray crystal structure determination of the first structurally authenticated terphenyl gold complex”. INORGANICA CHIMICA ACTA 316.1-2 (2001): 132-134.
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