Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium

Mitzel NW, Losehand U (2001)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 56(7): 630-633.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
The compound (Me2NO)(3)SiOSi(ONMe2)(3) was prepared by the reaction of LiONMe2 with Si2Cl6, a reaction in which oxygen is inserted into the Si-Si bond. The crystal structure of (Me2NO)(3)SiOSi(ONMe2)(3) was determined and shows the compound to have a linear siloxane core and SiON units with small valence angles at oxygen, caused by weak Si .(.N interactions leading to partially hypercoordinate Si centres.
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Erscheinungsjahr
Zeitschriftentitel
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
Band
56
Zeitschriftennummer
7
Seite
630-633
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PUB-ID

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Mitzel NW, Losehand U. Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2001;56(7):630-633.
Mitzel, N. W., & Losehand, U. (2001). Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 56(7), 630-633.
Mitzel, N. W., and Losehand, U. (2001). Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 56, 630-633.
Mitzel, N.W., & Losehand, U., 2001. Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 56(7), p 630-633.
N.W. Mitzel and U. Losehand, “Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 56, 2001, pp. 630-633.
Mitzel, N.W., Losehand, U.: Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 56, 630-633 (2001).
Mitzel, Norbert W., and Losehand, U. “Hexakis(dimethylaminoxy)disiloxane: Insertion of an oxygen atom into the Si-Si bond of a disilane by dimethylaminoxy lithium”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 56.7 (2001): 630-633.