(4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes

Mitzel NW, Vojinovic K (2002)
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (11): 2341-2343.

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Abstract
The compounds Ge(ONMe2)(4) and Ge(ONEt2)(4) were prepared by the reaction of LiONMe2 and LiONEt2 with GeCl4. They were characterized by H-1 and C-13 NMR and IR spectroscopy, by their decay patterns in the mass spectra, by high-resolution mass spectrometry and by elemental analyses. The crystal structure of Ge(ONMe2)(4) was determined and shows the compound to have a (4+4) coordinate germanium atom as is evident from the Ge-O-N angles, which are in the range between 100.8(3) and 109.2(4)degrees, which is on average 15.2degrees smaller than the Ge-O-C angles in Ge(ONCHMe2)(4). This compound was also prepared and examined by single crystal X-ray crystallography.
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Mitzel NW, Vojinovic K. (4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS. 2002;(11):2341-2343.
Mitzel, N. W., & Vojinovic, K. (2002). (4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS(11), 2341-2343.
Mitzel, N. W., and Vojinovic, K. (2002). (4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2341-2343.
Mitzel, N.W., & Vojinovic, K., 2002. (4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, (11), p 2341-2343.
N.W. Mitzel and K. Vojinovic, “(4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes”, JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, pp. 2341-2343.
Mitzel, N.W., Vojinovic, K.: (4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS. 2341-2343 (2002).
Mitzel, Norbert W., and Vojinovic, K. “(4+4)-Coordinate germanium atoms in tetrakis(dialkylaminoxy)-germanes”. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS 11 (2002): 2341-2343.
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