Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds

Westerhausen M, Weinrich S, Ossberger M, Mitzel NW (2003)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 629(4): 575-577.

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The reaction of calcium-bis[bis(trimethylsilyl)amide] with two equivalents triethylgallium yields nearly quantitatively the addition product. In the solid state the calcium atoms are coordinated by two nitrogen atoms and two ethyl groups, whereas in solution all ethyl substituents are magnetically equivalent even at low temperatures. The Ca-C-Ga two-electron three-center bonds show mean Ca-N and Ca-C distances of 243 and 268 pm, respectively.
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Westerhausen M, Weinrich S, Ossberger M, Mitzel NW. Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 2003;629(4):575-577.
Westerhausen, M., Weinrich, S., Ossberger, M., & Mitzel, N. W. (2003). Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 629(4), 575-577.
Westerhausen, M., Weinrich, S., Ossberger, M., and Mitzel, N. W. (2003). Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 629, 575-577.
Westerhausen, M., et al., 2003. Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 629(4), p 575-577.
M. Westerhausen, et al., “Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 629, 2003, pp. 575-577.
Westerhausen, M., Weinrich, S., Ossberger, M., Mitzel, N.W.: Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 629, 575-577 (2003).
Westerhausen, M, Weinrich, S, Ossberger, M, and Mitzel, Norbert W. “Calcium bis[bis(trimethylsilyl)amino-triethylgallate] - A molecule with Ca-C-Ga three-center bonds”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 629.4 (2003): 575-577.
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