Different modes of aggregation in organoaluminium and -gallium hydroxylamides

Mitzel NW, Lustig C, Woski M (2004)
DALTON TRANSACTIONS (3): 397-401.

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The organoaluminium and - gallium hydroxylamides (Me2GaONMe2)(2), (tBu(2)AlONMe(2))(2), (tBu(2)GaONMe(2))(2) and ((Me2AlONPr2)-Pr-i)(2) have been prepared by the reaction of the hydroxylamines Me2NOH and (Pr2NOH)-Pr-i with the trialkylmetal compounds trimethylgallium, tri- tbutylaluminium and tri- tbutylgallium, respectively. All compounds have been characterised by NMR spectroscopy (H-1, C-13, N-15, O-17 and Al-27), by mass spectrometry and elemental analyses. The crystal structures of the four compounds have been determined, showing that they all form dimers but with different modes of aggregation: (Me2GaONMe2)(2) has a Ga2O2N2 six-membered ring, ((Bu2AlONMe2)-Bu-t)(2) and ((Me2AlONPr2)-Pr-i)(2) have Al2O2 four-membered rings, ((Bu2GaONMe2)-Bu-t)(2) forms a Ga2O2N five-membered ring.
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Mitzel NW, Lustig C, Woski M. Different modes of aggregation in organoaluminium and -gallium hydroxylamides. DALTON TRANSACTIONS. 2004;(3):397-401.
Mitzel, N. W., Lustig, C., & Woski, M. (2004). Different modes of aggregation in organoaluminium and -gallium hydroxylamides. DALTON TRANSACTIONS(3), 397-401. doi:10.1039/b311781b
Mitzel, N. W., Lustig, C., and Woski, M. (2004). Different modes of aggregation in organoaluminium and -gallium hydroxylamides. DALTON TRANSACTIONS, 397-401.
Mitzel, N.W., Lustig, C., & Woski, M., 2004. Different modes of aggregation in organoaluminium and -gallium hydroxylamides. DALTON TRANSACTIONS, (3), p 397-401.
N.W. Mitzel, C. Lustig, and M. Woski, “Different modes of aggregation in organoaluminium and -gallium hydroxylamides”, DALTON TRANSACTIONS, 2004, pp. 397-401.
Mitzel, N.W., Lustig, C., Woski, M.: Different modes of aggregation in organoaluminium and -gallium hydroxylamides. DALTON TRANSACTIONS. 397-401 (2004).
Mitzel, Norbert W., Lustig, C, and Woski, M. “Different modes of aggregation in organoaluminium and -gallium hydroxylamides”. DALTON TRANSACTIONS 3 (2004): 397-401.
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Structural variations and molecular dynamics of rare-earth metal complexes with the N,N-bis(2-{pyrid-2-yl}ethyl)hydroxylaminato ligand.
Hellmann BJ, Venugopal A, Mix A, Neumann B, Stammler HG, Willner A, Pape T, Hepp A, Mitzel NW., Chemistry 15(43), 2009
PMID: 19774565

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