Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state

Mitzel NW, Losehand U (2004)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 59(6): 635-638.

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Abstract
The compounds (H3C)(2)S, (H3Si)(2)S and (H3Ge)(2)S have been crystallised in situ on a diffractometer and their crystal structures determined by low-temperature X-ray diffraction. The molecules are present as monomers in the crystals. The aggregation of the molecules through secondary intermolecular contacts in the crystal is different: (H3C)(2)S is weakly associated into dimers by S...S contacts, whereas (H3Si)(2)S and (H3Ge)(2)S form Si...S and Ge...S contacts in an ice-analogous aggregation motif. Important geometry parameters are (H3C)(2)S: C-S 1.794(av) Angstrom, C-S-C 99.2(1)degrees; (H3Si)(2)S: Si-S 2.143(1) Angstrom, Si-S-Si 98.4degrees; (H3Ge)(2)S Ge-S 2.223(2) and 2.230(2) Angstrom, Ge-S-Ge 98.2(1)degrees.
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Mitzel NW, Losehand U. Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2004;59(6):635-638.
Mitzel, N. W., & Losehand, U. (2004). Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 59(6), 635-638.
Mitzel, N. W., and Losehand, U. (2004). Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 59, 635-638.
Mitzel, N.W., & Losehand, U., 2004. Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 59(6), p 635-638.
N.W. Mitzel and U. Losehand, “Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 59, 2004, pp. 635-638.
Mitzel, N.W., Losehand, U.: Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 59, 635-638 (2004).
Mitzel, Norbert W., and Losehand, U. “Dimethyl-, disilyl- and digermylsulfide: Different intermolecular contacts in the solid state”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 59.6 (2004): 635-638.
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