The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides

Tian X, Fröhlich R, Mitzel NW (2005)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 60(3): 247-250.

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Abstract
The syntheses of dibutylaluminium and -gallium iodide via metathesis reactions of the respective chlorides with lithium iodide are reported. The compounds were identified by elemental analyses, multinuclear NMR spectroscopy (H-1, C-13, Al-27) and mass spectra (EI). The structures obtained by single crystal X-ray diffraction reveal that the new compound (Bu2AlI)-Bu-t crystallizes in the monoclinic crystal system, space group P2(1)/n, as a dimer with a planar Al2I2 four-membered ring. The crystal structure of the monoclinic structure of (Bu2GaI)-Bu-t was redetermined. Its mass spectra reveal the existence of trimers and dimers in addition to the predominant monomeric species in gas phase.
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Tian X, Fröhlich R, Mitzel NW. The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 2005;60(3):247-250.
Tian, X., Fröhlich, R., & Mitzel, N. W. (2005). The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 60(3), 247-250.
Tian, X., Fröhlich, R., and Mitzel, N. W. (2005). The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 60, 247-250.
Tian, X., Fröhlich, R., & Mitzel, N.W., 2005. The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 60(3), p 247-250.
X. Tian, R. Fröhlich, and N.W. Mitzel, “The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 60, 2005, pp. 247-250.
Tian, X., Fröhlich, R., Mitzel, N.W.: The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 60, 247-250 (2005).
Tian, X, Fröhlich, R, and Mitzel, Norbert W. “The crystal structures of dimeric di(tert-butyl)aluminium and -gallium iodides”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 60.3 (2005): 247-250.
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