Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates

Ullrich M, Berger R, Pape T, Mitzel NW (2006)
DALTON TRANSACTIONS (45): 5334-5336.

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Whereas (meso)-[(norcamphor oximato) GaMe2](2) (1) exhibits the dimeric M2O2N2 motif favoured by organo group 13 metal oximates, the Me2In derivative [{( meso)-[( norcamphor oximato) InMe2] 2} 2]8 (2) aggregates distinctly different with the In atoms adopting coordination number (CN) = 5; compound 2 is the first oximato-based chain-like coordination polymer in group 13 organometallics; it comprises alternating M2O2N2 and M2O2 ring dimers interconnected via two types of a fifth dative bond (O. In and N. In) to yield the new {M4O4N4}(infinity) motif; the calculated energetics of the heteroatom rings involved in 1 and 2 confirm the diverging aggregational behaviour of Ga and In.
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Ullrich M, Berger R, Pape T, Mitzel NW. Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates. DALTON TRANSACTIONS. 2006;(45):5334-5336.
Ullrich, M., Berger, R., Pape, T., & Mitzel, N. W. (2006). Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates. DALTON TRANSACTIONS(45), 5334-5336.
Ullrich, M., Berger, R., Pape, T., and Mitzel, N. W. (2006). Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates. DALTON TRANSACTIONS, 5334-5336.
Ullrich, M., et al., 2006. Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates. DALTON TRANSACTIONS, (45), p 5334-5336.
M. Ullrich, et al., “Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates”, DALTON TRANSACTIONS, 2006, pp. 5334-5336.
Ullrich, M., Berger, R., Pape, T., Mitzel, N.W.: Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates. DALTON TRANSACTIONS. 5334-5336 (2006).
Ullrich, Matthias, Berger, Raphael, Pape, Tania, and Mitzel, Norbert W. “Expectation and surprise in group 13 organometallics: molecular vs. polymeric aggregation of Me2Ga and Me2In norcamphor oximates”. DALTON TRANSACTIONS 45 (2006): 5334-5336.
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Structure and formation of the first (-O-Te-N-)4 ring.
Kubel J, Elder PJ, Jenkins HA, Vargas-Baca I., Dalton Trans 39(46), 2010
PMID: 20976347

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