Nitrogen compounds and their influence on diamond deposition in flames

Atakan B, Beuger M, Kohse-Höinghaus K (1999)
physical chemistry chemical physics 1(4): 705-708.

Journal Article | Published | English

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Abstract
The influence of nitrogen-containing species on the growth of diamond films is well-established in microwave and hot filament chemical vapour deposition (CVD) systems. Here, diamond CVD was investigated in atmospheric acetylene-oxygen flames doped with N-containing species [N-2, N2O, NH3, N(CH3)(3)]. Small amounts of these additives increase the growth rate, while higher concentrations lead to preferential sp(2) carbon deposition. The growth-effective amount of N-additive decreases by more than an order of magnitude in the sequence N-2 > N(CH3)(3) congruent to N2O > NH3. Simulation of the gas phase chemistry in a stagnation-flow geometry shows that the transformation of the additives towards HCN, NO and N is strongly correlated with growth enhancement and film quality decrease.
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Atakan B, Beuger M, Kohse-Höinghaus K. Nitrogen compounds and their influence on diamond deposition in flames. physical chemistry chemical physics. 1999;1(4):705-708.
Atakan, B., Beuger, M., & Kohse-Höinghaus, K. (1999). Nitrogen compounds and their influence on diamond deposition in flames. physical chemistry chemical physics, 1(4), 705-708.
Atakan, B., Beuger, M., and Kohse-Höinghaus, K. (1999). Nitrogen compounds and their influence on diamond deposition in flames. physical chemistry chemical physics 1, 705-708.
Atakan, B., Beuger, M., & Kohse-Höinghaus, K., 1999. Nitrogen compounds and their influence on diamond deposition in flames. physical chemistry chemical physics, 1(4), p 705-708.
B. Atakan, M. Beuger, and K. Kohse-Höinghaus, “Nitrogen compounds and their influence on diamond deposition in flames”, physical chemistry chemical physics, vol. 1, 1999, pp. 705-708.
Atakan, B., Beuger, M., Kohse-Höinghaus, K.: Nitrogen compounds and their influence on diamond deposition in flames. physical chemistry chemical physics. 1, 705-708 (1999).
Atakan, Burak, Beuger, Michael, and Kohse-Höinghaus, Katharina. “Nitrogen compounds and their influence on diamond deposition in flames”. physical chemistry chemical physics 1.4 (1999): 705-708.
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