Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks

DeBurgomaster P, Bartholomae M, Raffel R, Ouellette W, Müller A, Zubieta J (2010)
INORGANICA CHIMICA ACTA 363(7): 1386-1394.

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Abstract
The reactions of the Keplerate super cluster [Mo132O372(CH3CO2)(30)(H2O)(72)](42) with a Cu(II) source and an organonitrogen donor in methanol/DMF solutions yielded a series of bimetallic organic-inorganic oxide hybrid materials, including the molecular species [Cu(phen)(2)MoO4] (1) and [{Cu(terpy)}(2)(MoO4)(2)] (2) and a series of materials constructed from the tetranuclear building block {Mo4O10(OMe)(6)}(2) : the molecular [{Cu-2(phen)(2)(O2CCH3)(2) (MeOH)} Mo4O10(OMe)(6)] (3), [{Cu(terpy)(O2CCH3)}(2)Mo4O10(OMe)(6)] (4) and [{Cu(terpy)Cl}(2)Mo4O10(OMe)(6)] (5), the one-dimensional phases [{Cu(bpy)(HOMe)(2)}Mo4O10(OMe)(6)] (6), [{Cu(bpy)(DMF)(2)}Mo4O10(OMe)(6)] (7), [{Cu(bpa)(DMF)(2)}Mo4O10(OMe)(6)] (8), [{Cu(phen)(DMF)(2)}Mo4O10-(OMe)(6)] (9) and [{CuCl(dpa)}(2)Mo4O10(OMe)(6)] (10), and the two-dimensional material [{Cu-2(DMF)(2)(pd-pa)}{Mo4O10(OMe)(6)}(2)] (11). When methanol is replaced by the tridentate alkoxide tris-methoxypropane (trisp), the {Mo2O4(trisp)(2)}(2) cluster building block is observed for [Cu(phen)Mo2O4(trisp)(2)] (12), [Cu(bpa) (DMF)Mo2O4(trisp)(2)] (13) and [{Cu(bpy)(NO3)}(2)Mo2O4(trisp)(2)] (14). (C) 2010 Elsevier B.V. All rights reserved.
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DeBurgomaster P, Bartholomae M, Raffel R, Ouellette W, Müller A, Zubieta J. Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks. INORGANICA CHIMICA ACTA. 2010;363(7):1386-1394.
DeBurgomaster, P., Bartholomae, M., Raffel, R., Ouellette, W., Müller, A., & Zubieta, J. (2010). Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks. INORGANICA CHIMICA ACTA, 363(7), 1386-1394.
DeBurgomaster, P., Bartholomae, M., Raffel, R., Ouellette, W., Müller, A., and Zubieta, J. (2010). Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks. INORGANICA CHIMICA ACTA 363, 1386-1394.
DeBurgomaster, P., et al., 2010. Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks. INORGANICA CHIMICA ACTA, 363(7), p 1386-1394.
P. DeBurgomaster, et al., “Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks”, INORGANICA CHIMICA ACTA, vol. 363, 2010, pp. 1386-1394.
DeBurgomaster, P., Bartholomae, M., Raffel, R., Ouellette, W., Müller, A., Zubieta, J.: Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks. INORGANICA CHIMICA ACTA. 363, 1386-1394 (2010).
DeBurgomaster, Paul, Bartholomae, Mark, Raffel, Ryan, Ouellette, Wayne, Müller, Achim, and Zubieta, Jon. “Coordination chemistry of copper-molybdates with alkoxide ligands: The {Mo4O10(OMe)(6)}(2-) and [Mo2O4{RC(CH2O)(3)}(2)](2-) clusters as building blocks”. INORGANICA CHIMICA ACTA 363.7 (2010): 1386-1394.
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