On the Molecular and Electronic Structures of AsP3 and P-4

Cossairt BM, Cummins CC, Head AR, Lichtenberger DL, Berger R, Hayes SA, Mitzel NW, Wu G (2010)
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132(24): 8459-8465.

Download
Es wurde kein Volltext hochgeladen. Nur Publikationsnachweis!
Zeitschriftenaufsatz | Veröffentlicht | Englisch
Autor
; ; ; ; ; ; ;
Abstract / Bemerkung
The molecular and electronic structures of AsP3 and P-4 have been investigated. Gas-phase electron diffraction studies of AsP3 have provided r(g) bond lengths of 2.3041(12) and 2.1949(28) angstrom for the As-P interatomic distances and the P-P interatomic distances, respectively. The gas-phase electron diffraction structure of P-4 has been redetermined and provides an updated value of 2.1994(3) angstrom for the P-P interatomic distances, reconciling conflicting literature values. Gas-phase photoelectron spectroscopy provides experimental values for the energies of ionizations from the valence molecular orbitals of AsP3 and P-4 and shows that electronically AsP3 and P-4 are quite similar. Solid-state As-75 and P-31 NMR spectroscopy demonstrate the plastic nature of AsP3 and P-4 as solids, and an extreme upfield As-75 chemical shift has been confirmed for the As atom in AsP3. Finally, quantum chemical gauge-including magnetically induced current calculations show that AsP3 and P-4 can accurately be described as strongly aromatic. Together these data provide a cohesive description of the molecular and electronic properties of these two tetraatomic molecules.
Erscheinungsjahr
Zeitschriftentitel
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Band
132
Zeitschriftennummer
24
Seite
8459-8465
ISSN
eISSN
PUB-ID

Zitieren

Cossairt BM, Cummins CC, Head AR, et al. On the Molecular and Electronic Structures of AsP3 and P-4. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2010;132(24):8459-8465.
Cossairt, B. M., Cummins, C. C., Head, A. R., Lichtenberger, D. L., Berger, R., Hayes, S. A., Mitzel, N. W., et al. (2010). On the Molecular and Electronic Structures of AsP3 and P-4. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(24), 8459-8465. doi:10.1021/ja102580d
Cossairt, B. M., Cummins, C. C., Head, A. R., Lichtenberger, D. L., Berger, R., Hayes, S. A., Mitzel, N. W., and Wu, G. (2010). On the Molecular and Electronic Structures of AsP3 and P-4. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132, 8459-8465.
Cossairt, B.M., et al., 2010. On the Molecular and Electronic Structures of AsP3 and P-4. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 132(24), p 8459-8465.
B.M. Cossairt, et al., “On the Molecular and Electronic Structures of AsP3 and P-4”, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 132, 2010, pp. 8459-8465.
Cossairt, B.M., Cummins, C.C., Head, A.R., Lichtenberger, D.L., Berger, R., Hayes, S.A., Mitzel, N.W., Wu, G.: On the Molecular and Electronic Structures of AsP3 and P-4. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 132, 8459-8465 (2010).
Cossairt, Brandi M., Cummins, Christopher C., Head, Ashley R., Lichtenberger, Dennis L., Berger, Raphael, Hayes, Stuart A., Mitzel, Norbert W., and Wu, Gang. “On the Molecular and Electronic Structures of AsP3 and P-4”. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 132.24 (2010): 8459-8465.

15 Zitationen in Europe PMC

Daten bereitgestellt von Europe PubMed Central.

Nacnac-Cobalt-Mediated P4 Transformations.
Spitzer F, Graßl C, Balázs G, Mädl E, Keilwerth M, Zolnhofer EM, Meyer K, Scheer M., Chemistry 23(11), 2017
PMID: 28032678
Functionalization of P4 through Direct P-C Bond Formation.
Borger JE, Ehlers AW, Slootweg JC, Lammertsma K., Chemistry 23(49), 2017
PMID: 28497639
Functionalization of P4 in the coordination sphere of coinage metal cations.
Borger JE, Bakker MS, Ehlers AW, Lutz M, Slootweg JC, Lammertsma K., Chem Commun (Camb) 52(16), 2016
PMID: 26750104
Probing the Structure, Dynamics, and Bonding of Coinage Metal Complexes of White Phosphorus.
Forfar LC, Zeng D, Green M, McGrady JE, Russell CA., Chemistry 22(15), 2016
PMID: 26918670
Influence of the nacnac Ligand in Iron(I)-Mediated P4 Transformations.
Spitzer F, Graßl C, Balázs G, Zolnhofer EM, Meyer K, Scheer M., Angew Chem Int Ed Engl 55(13), 2016
PMID: 26924606
Safe P₄ reagent in a reusable porous coordination network.
Choi W, Ohtsu H, Matsushita Y, Kawano M., Dalton Trans 45(15), 2016
PMID: 27008184
Unusual acid-base properties of the P4 molecule in hydrogen-, halogen-, and pnicogen-bonded complexes.
Alkorta I, Elguero J, Del Bene JE., Phys Chem Chem Phys 18(47), 2016
PMID: 27874896
Fixation and release of intact E₄ tetrahedra (E=P, As).
Spitzer F, Sierka M, Latronico M, Mastrorilli P, Virovets AV, Scheer M., Angew Chem Int Ed Engl 54(14), 2015
PMID: 25677593
Stabilization of tetrahedral P₄ and As₄ molecules as guests in polymeric and spherical environments.
Schwarzmaier C, Schindler A, Heindl C, Scheuermayer S, Peresypkina EV, Virovets AV, Neumeier M, Gschwind R, Scheer M., Angew Chem Int Ed Engl 52(41), 2013
PMID: 24000137
P4 activation by group 3 metal arene complexes.
Huang W, Diaconescu PL., Chem Commun (Camb) 48(16), 2012
PMID: 22252468
New chemistry of 1,2-closo-P2B10H10 and 1,2-closo-As2B10H10; in silico and gas electron diffraction structures, and new metalladiphospha- and metalladiarsaboranes.
McLellan R, Boag NM, Dodds K, Ellis D, Macgregor SA, McKay D, Masters SL, Noble-Eddy R, Platt NP, Rankin DW, Robertson HE, Rosair GM, Welch AJ., Dalton Trans 40(27), 2011
PMID: 21666895
Dynamic behaviour of Ru and Ru-Pt complexes containing tetrahedro-P4 ligand.
Mirabello V, Caporali M, Gallo V, Gonsalvi L, Ienco A, Latronico M, Mastrorilli P, Peruzzini M., Dalton Trans 40(38), 2011
PMID: 21863192
The gauge including magnetically induced current method.
Fliegl H, Taubert S, Lehtonen O, Sundholm D., Phys Chem Chem Phys 13(46), 2011
PMID: 21909556
Ring currents in the dismutational aromatic Si6R6.
Berger RJ, Rzepa HS, Scheschkewitz D., Angew Chem Int Ed Engl 49(51), 2010
PMID: 21082630

Export

Markieren/ Markierung löschen
Markierte Publikationen

Open Data PUB

Web of Science

Dieser Datensatz im Web of Science®

Quellen

PMID: 20515032
PubMed | Europe PMC

Suchen in

Google Scholar