Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine

Berger R, Mitzel NW (2010)
JOURNAL OF MOLECULAR STRUCTURE 978(1-3): 205-208.

Journal Article | Published | English

No fulltext has been uploaded

Abstract
The gas-phase structure of tris(trifluoromethyl)arsine (As(CF3)(3)) at ambient temperature has been reinvestigated by means of electron diffraction. Substantial higher accuracy in structural parameters compared to the previous investigation has been achieved. In contrast to the previously reported C-3v structure we found C-3 symmetry. Selected r(a3,1) structure parameters are: As-C = 2.007(2) angstrom; C-As-C = 95.5(3)degrees. The experimental structure parameters are compared to parameters obtained in HF/TZVPP and MP2/TZVPP calculations, the latter being in excellent agreement with the experimental structure. (C) 2010 Elsevier B.V. All rights reserved.
Publishing Year
ISSN
PUB-ID

Cite this

Berger R, Mitzel NW. Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE. 2010;978(1-3):205-208.
Berger, R., & Mitzel, N. W. (2010). Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE, 978(1-3), 205-208.
Berger, R., and Mitzel, N. W. (2010). Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE 978, 205-208.
Berger, R., & Mitzel, N.W., 2010. Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE, 978(1-3), p 205-208.
R. Berger and N.W. Mitzel, “Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine”, JOURNAL OF MOLECULAR STRUCTURE, vol. 978, 2010, pp. 205-208.
Berger, R., Mitzel, N.W.: Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine. JOURNAL OF MOLECULAR STRUCTURE. 978, 205-208 (2010).
Berger, Raphael, and Mitzel, Norbert W. “Reinvestigation of the gas-phase structure of tris(trifluoromethyl)arsine”. JOURNAL OF MOLECULAR STRUCTURE 978.1-3 (2010): 205-208.
This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar