Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes

Strasser U, Neumann B, Stammler H-G, Mitzel NW (2010)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 636(7): 1249-1254.

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Abstract
The tetrasilyl ethers calix[4]areneOSiMe(2)R (R = Me, H, vinyl, allyl) were prepared by salt elimination; the calix[4]arene was deprotonated with sodium hydride and subsequently reacted with chlorosilanes CISiMe2R. In general, DMF was chosen as solvent in order to steer the reactions in terms of a preference for the cone-conformation of the products. In the case of calix[4]areneOSiMe(3) both, partial-cone-and cone-conformers, were synthesised. All products were characterised by NMR H-1, C-13, Si-29) spectroscopy, mass spectrometry and single-crystal X-ray diffraction.
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Strasser U, Neumann B, Stammler H-G, Mitzel NW. Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 2010;636(7):1249-1254.
Strasser, U., Neumann, B., Stammler, H. - G., & Mitzel, N. W. (2010). Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 636(7), 1249-1254.
Strasser, U., Neumann, B., Stammler, H. - G., and Mitzel, N. W. (2010). Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 636, 1249-1254.
Strasser, U., et al., 2010. Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 636(7), p 1249-1254.
U. Strasser, et al., “Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 636, 2010, pp. 1249-1254.
Strasser, U., Neumann, B., Stammler, H.-G., Mitzel, N.W.: Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 636, 1249-1254 (2010).
Strasser, Ulf, Neumann, Beate, Stammler, Hans-Georg, and Mitzel, Norbert W. “Synthesis and Molecular Structures of Tetrasilyl Ethers of Calix[4]arenes”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 636.7 (2010): 1249-1254.
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