Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes

Niu W-X, Wang T, Hou Q-Q, Li Z-Y, Cao X-P, Kuck D (2010)
JOURNAL OF ORGANIC CHEMISTRY 75(19): 6704-6707.

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The synthesis of several inherently chiral tribenzotriquinacenes (TBTQs) bearing one single mono- or difunctionalized aromatic nucleus and the optical resolution of one of these derivatives, a TBTQ-based salicylic acid (11), are described for the first time. Efficient access to enantio-pure, inherently chiral tribenzotriquinacenes may lay a foundation for studies of novel container compounds, supramolecular aggregation, chiral recognition, and asymmetric catalysis.
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Niu W-X, Wang T, Hou Q-Q, Li Z-Y, Cao X-P, Kuck D. Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes. JOURNAL OF ORGANIC CHEMISTRY. 2010;75(19):6704-6707.
Niu, W. - X., Wang, T., Hou, Q. - Q., Li, Z. - Y., Cao, X. - P., & Kuck, D. (2010). Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes. JOURNAL OF ORGANIC CHEMISTRY, 75(19), 6704-6707.
Niu, W. - X., Wang, T., Hou, Q. - Q., Li, Z. - Y., Cao, X. - P., and Kuck, D. (2010). Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes. JOURNAL OF ORGANIC CHEMISTRY 75, 6704-6707.
Niu, W.-X., et al., 2010. Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes. JOURNAL OF ORGANIC CHEMISTRY, 75(19), p 6704-6707.
W.-X. Niu, et al., “Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes”, JOURNAL OF ORGANIC CHEMISTRY, vol. 75, 2010, pp. 6704-6707.
Niu, W.-X., Wang, T., Hou, Q.-Q., Li, Z.-Y., Cao, X.-P., Kuck, D.: Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes. JOURNAL OF ORGANIC CHEMISTRY. 75, 6704-6707 (2010).
Niu, Wen-Xue, Wang, Tao, Hou, Qin-Qing, Li, Zi-Yang, Cao, Xiao-Ping, and Kuck, Dietmar. “Synthesis and Optical Resolution of Inherently Chiral Difunctionalized Tribenzotriquinacenes”. JOURNAL OF ORGANIC CHEMISTRY 75.19 (2010): 6704-6707.
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Unidirectional molecular stacking of tribenzotriquinacenes in the solid state: a combined X-ray and theoretical study.
Brandenburg JG, Grimme S, Jones PG, Markopoulos G, Hopf H, Cyranski MK, Kuck D., Chemistry 19(30), 2013
PMID: 23766137
Tribenzotriquinacene: a versatile synthesis and C3-chiral platforms.
Markopoulos G, Henneicke L, Shen J, Okamoto Y, Jones PG, Hopf H., Angew. Chem. Int. Ed. Engl. 51(51), 2012
PMID: 23144000

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