Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia

Kovácik V, Hirsch J, Thölmann D, Grützmacher H-F (1991)
Organic Mass Spectrometry 26(12): 1085-1088.

Download
OA
Journal Article | Published | English
Author
; ; ;
Abstract
Glycosidic oxocarbenium ions A1+ were formed by isobutane chemical ionization from methyl 2,3,4,6-tetra-O-methyl-beta-D-mannopyranoside, methyl 2,3,4,6-tetra-O-methyl-beta-D-galactopyranoside and methyl 2,3,4,6-tetra-O-methyl-beta-D-glucopyranoside (the ring -O-being converted into -O+=), and their reaction with ammonia was studied by Fourier transform ion cyclotron resonance spectrometry. Very slow formation (reaction efficiency 0.6-1.4%) of the adduct ion [A1 + NH3]+ was observed as the main process for carefully thermalized ions A1+. Interestingly, the efficiency of the adduct ion formation depends on the sterochemistry of ions A1+.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Kovácik V, Hirsch J, Thölmann D, Grützmacher H-F. Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia. Organic Mass Spectrometry. 1991;26(12):1085-1088.
Kovácik, V., Hirsch, J., Thölmann, D., & Grützmacher, H. - F. (1991). Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia. Organic Mass Spectrometry, 26(12), 1085-1088.
Kovácik, V., Hirsch, J., Thölmann, D., and Grützmacher, H. - F. (1991). Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia. Organic Mass Spectrometry 26, 1085-1088.
Kovácik, V., et al., 1991. Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia. Organic Mass Spectrometry, 26(12), p 1085-1088.
V. Kovácik, et al., “Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia”, Organic Mass Spectrometry, vol. 26, 1991, pp. 1085-1088.
Kovácik, V., Hirsch, J., Thölmann, D., Grützmacher, H.-F.: Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia. Organic Mass Spectrometry. 26, 1085-1088 (1991).
Kovácik, Vladimir, Hirsch, Janos, Thölmann, Detlef, and Grützmacher, Hans-Friedrich. “Fourier transform ion cyclotron resonance study of ion-molecule reactions of [M - OCH 3] + ions of methyl 2,3,4,6-tetra-O-methyl-d-hexopyranosides with ammonia”. Organic Mass Spectrometry 26.12 (1991): 1085-1088.
Main File(s)
File Name
Access Level
OA Open Access

This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar