[Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure

Jutzi P, Becker A, Leue C, Stammler H-G, Neumann B, Hursthouse MB, Karaulov A (1991)
Organometallics 10(11): 3838-3842.

Download
OA
Journal Article | Published | English
Author
; ; ; ; ; ;
Abstract
(Pentamethylcyclopentadieny1)germanium chloride (1) reacts with (tris(trimethylsily1)methyl)lithium to give (pentamethylcyclopentadienyl) (tris(trimethylsily1)methyl)germylene (3) and with (2,4,6-tri-tertbutylpheny1) lithium to yield (pentamethylcyclopentadienyl)(2,4,6-tri-tert-butylphenyl)germylen(4). Both germylenes (3 and 4) are monomeric with a fluxional [eta]2 bonding between the germanium center and the Me5C5 ring. Compound 3 crystallizes in the monoclinic space group P21/c with unit cell dimensions a = 9.954 (1) Å, b = 8.759 (2), Å, c = 29.416 (6) Å, [beta] = 95.05 (2)°, and Z = 4. Complex 4 crystallizes in the monoclinic space group P21/n with unit cell dimensions a = 10.404 (5) Å, b = 13.519 (6) Å, c = 19.203 (10) Å, [beta] = 103.62 (4)°, and Z = 4.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Jutzi P, Becker A, Leue C, et al. [Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure. Organometallics. 1991;10(11):3838-3842.
Jutzi, P., Becker, A., Leue, C., Stammler, H. - G., Neumann, B., Hursthouse, M. B., & Karaulov, A. (1991). [Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure. Organometallics, 10(11), 3838-3842.
Jutzi, P., Becker, A., Leue, C., Stammler, H. - G., Neumann, B., Hursthouse, M. B., and Karaulov, A. (1991). [Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure. Organometallics 10, 3838-3842.
Jutzi, P., et al., 1991. [Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure. Organometallics, 10(11), p 3838-3842.
P. Jutzi, et al., “[Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure”, Organometallics, vol. 10, 1991, pp. 3838-3842.
Jutzi, P., Becker, A., Leue, C., Stammler, H.-G., Neumann, B., Hursthouse, M.B., Karaulov, A.: [Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure. Organometallics. 10, 3838-3842 (1991).
Jutzi, Peter, Becker, Anke, Leue, Christian, Stammler, Hans-Georg, Neumann, Beate, Hursthouse, Michael B., and Karaulov, Alexander. “[Tris(trimethylsilyl)methyl]- and (2,4,6-tri-tert-butylphenyl)(pentamethylcyclopentadienyl)germylene: synthesis and structure”. Organometallics 10.11 (1991): 3838-3842.
Main File(s)
Access Level
OA Open Access

This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar