Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]

Weber L, Kirchhoff R, Stammler H-G, Neumann B (1992)
Chemische Berichte 125(7): 1553-1557.

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Journal Article | Published | German
Abstract
(eta-5-C5Me5)(CO)2FePH2 (5), prepared from (eta-5-C5Me5)(CO)2Fe-P(SiMe3)2 and ethanol, reacts with one equivalent of ClP = C(SiMe3)2 to give the diphosphirane (eta-5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH (8). Compound 8 is converted into the iron chromium complex [(eta-5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH]-Cr(CO)5 (9). In contrast, the reaction of 5 with two equivalents of ClP=C(SiMe3)2 results in the formation of the cyclotriphosphane [(eta-5-C5Me5)(CO)2Fe-P]2P[CH(SiMe3)2] (12). The molecular structure of 9 is elucidated by single-crystal X-ray analysis.
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Weber L, Kirchhoff R, Stammler H-G, Neumann B. Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]. Chemische Berichte. 1992;125(7):1553-1557.
Weber, L., Kirchhoff, R., Stammler, H. - G., & Neumann, B. (1992). Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]. Chemische Berichte, 125(7), 1553-1557.
Weber, L., Kirchhoff, R., Stammler, H. - G., and Neumann, B. (1992). Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]. Chemische Berichte 125, 1553-1557.
Weber, L., et al., 1992. Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]. Chemische Berichte, 125(7), p 1553-1557.
L. Weber, et al., “Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]”, Chemische Berichte, vol. 125, 1992, pp. 1553-1557.
Weber, L., Kirchhoff, R., Stammler, H.-G., Neumann, B.: Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]. Chemische Berichte. 125, 1553-1557 (1992).
Weber, Lothar, Kirchhoff, Ralf, Stammler, Hans-Georg, and Neumann, Beate. “Synthese und Struktur des Diphosphirans (η5-C5Me5)(CO)2Fe-P-C(SiMe3)2-PH[Cr(CO)5]”. Chemische Berichte 125.7 (1992): 1553-1557.
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