Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene

Eckrich R, Kuck D (1993)
Synlett 1993(05): 344-347.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
Four prototype centropolyindans 1, 3, 7, and 10 were subjected to reduction with Li/NH3 and Li/NH2Me. While Birch reduction of 1, 3, and 7 gives medium to good yields of the corresponding two-, three-, and sixfold 1,4-cyclohexadienes 2, 4, and 8, respectively, centrohexaindan 10 does not react at all. With Li in NH2Me, however, 10 is converted to the corresponding hexaene, the title compound 12. Similarly, Benkeser reductions of 1 and 7 give the corresponding triquinacene 6 and the [3.3.3]propellatriene 9. Preliminary epoxidation and hydrogenation experiments of some polycyclic olefins are presented.
Erscheinungsjahr
Zeitschriftentitel
Synlett
Band
1993
Zeitschriftennummer
05
Seite
344-347
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Eckrich R, Kuck D. Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett. 1993;1993(05):344-347.
Eckrich, R., & Kuck, D. (1993). Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett, 1993(05), 344-347. doi:10.1055/s-1993-22449
Eckrich, R., and Kuck, D. (1993). Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett 1993, 344-347.
Eckrich, R., & Kuck, D., 1993. Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett, 1993(05), p 344-347.
R. Eckrich and D. Kuck, “Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene”, Synlett, vol. 1993, 1993, pp. 344-347.
Eckrich, R., Kuck, D.: Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett. 1993, 344-347 (1993).
Eckrich, Ralf, and Kuck, Dietmar. “Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene”. Synlett 1993.05 (1993): 344-347.
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