Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene

Eckrich R, Kuck D (1993)
Synlett 1993(05): 344-347.

Download
OA
Journal Article | Published | English
Author
;
Abstract
Four prototype centropolyindans 1, 3, 7, and 10 were subjected to reduction with Li/NH3 and Li/NH2Me. While Birch reduction of 1, 3, and 7 gives medium to good yields of the corresponding two-, three-, and sixfold 1,4-cyclohexadienes 2, 4, and 8, respectively, centrohexaindan 10 does not react at all. With Li in NH2Me, however, 10 is converted to the corresponding hexaene, the title compound 12. Similarly, Benkeser reductions of 1 and 7 give the corresponding triquinacene 6 and the [3.3.3]propellatriene 9. Preliminary epoxidation and hydrogenation experiments of some polycyclic olefins are presented.
Publishing Year
ISSN
eISSN
PUB-ID

Cite this

Eckrich R, Kuck D. Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett. 1993;1993(05):344-347.
Eckrich, R., & Kuck, D. (1993). Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett, 1993(05), 344-347.
Eckrich, R., and Kuck, D. (1993). Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett 1993, 344-347.
Eckrich, R., & Kuck, D., 1993. Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett, 1993(05), p 344-347.
R. Eckrich and D. Kuck, “Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene”, Synlett, vol. 1993, 1993, pp. 344-347.
Eckrich, R., Kuck, D.: Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene. Synlett. 1993, 344-347 (1993).
Eckrich, Ralf, and Kuck, Dietmar. “Multiple Dissolving-Metal Reduction of Centropolyindans: Synthesis of a Hexakis(cyclohexano)centrohexaquinacene”. Synlett 1993.05 (1993): 344-347.
Main File(s)
File Name
Access Level
OA Open Access

This data publication is cited in the following publications:
This publication cites the following data publications:

Export

0 Marked Publications

Open Data PUB

Web of Science

View record in Web of Science®

Search this title in

Google Scholar