Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan

Ceccon A, Gambaro A, Manoli F, Venzo A, Ganis P, Valle G, Kuck D (1993)
Chemische Berichte 126(9): 2053-2060.

Download
OA
Zeitschriftenaufsatz | Veröffentlicht | Englisch
Autor
; ; ; ; ; ;
Abstract / Bemerkung
The reaction of 9H,10H-4b,9a([1,2]benzenomethano)indeno[1,2-a]indene (triptindan, TRIP) with Cr(CO)6 in Bu2O/THF (9:1) affords a monocomplex (A) together with two bis-Cr(CO)3 complexes (B and C) and one tris-Cr(CO)3 complex (D). The relative yields of the four complexes as well as their tendency to lose Cr(CO)3 are related to stabilizing intramolecular factors. All the Cr(CO)3 units of the complexes A, B, and D are coordinated in the isoclined orientation with respect to the polar axis of the ligand, whereas complex C bears one isoclined and one anticlined Cr(CO)3 unit. The results of X-ray measurements support the hypothesis of weak attractive electronic interactions bonds between the oxygen atoms of the carbonyl groups and polarized faces of benzene rings.
Erscheinungsjahr
Zeitschriftentitel
Chemische Berichte
Band
126
Zeitschriftennummer
9
Seite
2053-2060
ISSN
eISSN
PUB-ID

Zitieren

Ceccon A, Gambaro A, Manoli F, et al. Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan. Chemische Berichte. 1993;126(9):2053-2060.
Ceccon, A., Gambaro, A., Manoli, F., Venzo, A., Ganis, P., Valle, G., & Kuck, D. (1993). Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan. Chemische Berichte, 126(9), 2053-2060. doi:10.1002/cber.19931260915
Ceccon, A., Gambaro, A., Manoli, F., Venzo, A., Ganis, P., Valle, G., and Kuck, D. (1993). Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan. Chemische Berichte 126, 2053-2060.
Ceccon, A., et al., 1993. Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan. Chemische Berichte, 126(9), p 2053-2060.
A. Ceccon, et al., “Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan”, Chemische Berichte, vol. 126, 1993, pp. 2053-2060.
Ceccon, A., Gambaro, A., Manoli, F., Venzo, A., Ganis, P., Valle, G., Kuck, D.: Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan. Chemische Berichte. 126, 2053-2060 (1993).
Ceccon, Alberto, Gambaro, Alessandro, Manoli, Francesco, Venzo, Alfonso, Ganis, Paolo, Valle, Giovanni, and Kuck, Dietmar. “Tricarbonylchromium complexes of centropolyindans, 3. Synthesis and structural investigation of tricarbonylchromium mono-, bis-, and tris-Complexes of triptindan”. Chemische Berichte 126.9 (1993): 2053-2060.
Alle Dateien verfügbar unter der/den folgenden Lizenz(en):
Copyright Statement:
This Item is protected by copyright and/or related rights. [...]
Volltext(e)
Access Level
OA Open Access
Zuletzt Hochgeladen
1970-01-01T00:00:00Z