THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W)

Herberhold M, Jin GX, Müller A, Penk M (1991)
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 46(1): 25-34.

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Abstract
Tetraphenylphosphonium tetrathiometalates, (PPh4)2MS4 (M = Mo, W), react with MoO2(acac)2 (2:1) in boiling acetonitrile in redox processes to give mixed-crystal compounds (as expected) of the approximate composition (PPh4)2[Mo3O1.9S8.1] (1) and (PPh4)2[Mo1.4W1.6O1.3S8.3] (2), respectively. 1 and 2 were characterized by single crystal X-ray structure analyses. The various anions of 1 and 2 contain {M(VI)(mu-S)2Mo(IV)O(mu-S)2M(VI)} cores (M = Mo (1); Mo, W (2); bond angle M...Mo...M = 151.3-degrees (1), 152.2-154.3-degrees (2)), which have high formation tendencies. The terminal positions are occupied by S and O atoms. The trinuclear anions of 1 correspond to the type [XYMo(mu-S)2MoO(mu-S)2MoSX]2- (X = O, S; Y = S, S2). In 2 there are two sets of anions of the type [XYM(mu-S)2MoO(mu-S)2WS2]2- and [ZSM(mu-S)2MoO(mu-S)2MZS]2- (Z = S(n)/O(m)) in the ratio of 2:1, occupying two symmetry-independent sites in the unit cell. Complex 2 is the first structurally characterized mixed-metal Mo-W thiometalate.
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Herberhold M, Jin GX, Müller A, Penk M. THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 1991;46(1):25-34.
Herberhold, M., Jin, G. X., Müller, A., & Penk, M. (1991). THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 46(1), 25-34.
Herberhold, M., Jin, G. X., Müller, A., and Penk, M. (1991). THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 46, 25-34.
Herberhold, M., et al., 1991. THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 46(1), p 25-34.
M. Herberhold, et al., “THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W)”, ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, vol. 46, 1991, pp. 25-34.
Herberhold, M., Jin, G.X., Müller, A., Penk, M.: THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W). ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES. 46, 25-34 (1991).
Herberhold, M, Jin, G. X., Müller, Achim, and Penk, M. “THE REACTIONS OF DIOXOBIS(ACETYLACETONATO)MOLYBDENUM, MOO2(ACAC)2, WITH TETRATHIOMOLYBDATE AND TETRATHIOTUNGSTATE - HIGH FORMATION TENDENCY OF THE (MVI(MU-S)2MOIVO(MU-S)2MVI) GROUP AND THE [MVIS3(S2)]2- TYPE LIGAND (M = MO, W)”. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES 46.1 (1991): 25-34.
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