Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2

Jutzi P, Kroos R, Müller A, Bögge H, Penk M (1991)
Chemische Berichte 124(1): 75-81.

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Synthese und Struktur der Polycyclohexaphosphane P6(C5Me5)4 und P6(C5Me5)2
Abstract
The cyclotriphosphine (PC5Me5)3 (1) decomposes in boiling benzene to give the bicyclo[3.1.0]hexaphosphine P6(C5Me5)4 (2) which yields the tricyclo[3.1.0.0(2.6)]hexaphosphine P6(C5Me5)2 (3) in boiling xylene. The structures of 2 and 3 have been determined by P-31-, C-13-, and H-1-NMR spectroscopy and by X-ray crystallography. 3 represents the first member of a new class of polyphosphines. The specific thermolysis of 1 and 2 under comparatively mild conditions is based on the easy homolytic cleavage of P-C5Me5 bonds in these compounds.
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Jutzi P, Kroos R, Müller A, Bögge H, Penk M. Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2. Chemische Berichte. 1991;124(1):75-81.
Jutzi, P., Kroos, R., Müller, A., Bögge, H., & Penk, M. (1991). Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2. Chemische Berichte, 124(1), 75-81.
Jutzi, P., Kroos, R., Müller, A., Bögge, H., and Penk, M. (1991). Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2. Chemische Berichte 124, 75-81.
Jutzi, P., et al., 1991. Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2. Chemische Berichte, 124(1), p 75-81.
P. Jutzi, et al., “Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2”, Chemische Berichte, vol. 124, 1991, pp. 75-81.
Jutzi, P., Kroos, R., Müller, A., Bögge, H., Penk, M.: Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2. Chemische Berichte. 124, 75-81 (1991).
Jutzi, Peter, Kroos, Rainer, Müller, Achim, Bögge, Hartmut, and Penk, Michael. “Synthesis and Structure of the Polycyclohexaphosphines P6(C5Me5)4 and P6(C5Me5)2”. Chemische Berichte 124.1 (1991): 75-81.
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