[ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING

Müller A, DORING J, KHAN MI, WITTNEBEN V (1991)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 30(2): 210-212.

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Zeitschriftenaufsatz | Veröffentlicht | Englisch
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Abstract / Bemerkung
A surprisingly low V(iv)/V(v) ratio is present in the cluster anion of 1. Its structure (picture right; V black, As shaded, O open circles) may be described as a {AsV 12O38} unit with O(h) symmetry. It is formed from twelve VO6 octahedra sharing edges, which each also share a face with the central AsO6 octahedron. Two additional V = O groups cap the AsO6 octahedron. K7[As(v)V(v)12V(iv)2O40] . 12 H2O 1.
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Zeitschriftentitel
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH
Band
30
Zeitschriftennummer
2
Seite
210-212
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Müller A, DORING J, KHAN MI, WITTNEBEN V. [ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH. 1991;30(2):210-212.
Müller, A., DORING, J., KHAN, M. I., & WITTNEBEN, V. (1991). [ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 30(2), 210-212. doi:10.1002/anie.199102101
Müller, A., DORING, J., KHAN, M. I., and WITTNEBEN, V. (1991). [ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 30, 210-212.
Müller, A., et al., 1991. [ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 30(2), p 210-212.
A. Müller, et al., “[ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING”, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, vol. 30, 1991, pp. 210-212.
Müller, A., DORING, J., KHAN, M.I., WITTNEBEN, V.: [ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH. 30, 210-212 (1991).
Müller, Achim, DORING, J, KHAN, MI, and WITTNEBEN, V. “[ASVV12(V)V2(IV)O40]7-, A TOPOLOGICALLY INTERESTING, MIXED-VALENCE CLUSTER AS MODEL FOR VANADIUM MINERALS FORMED BY WEATHERING”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 30.2 (1991): 210-212.