SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]

Jutzi P, WEGENER D, HURSTHOUSE M (1991)
JOURNAL OF ORGANOMETALLIC CHEMISTRY 418(3): 277-289.

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Abstract
The lithium salt Li2[Me2C2B9H9] reacts with the element(III) chlorides PCl3 and AsCl3 to yield the heterodicarbollyl compounds 1 and 2, respectively, of the type ClEl[Me2C2B9H9] (1, El = P; 2, El = As). Reaction of 1 and 2 with (i)PrMgCl leads to the corresponding isopropyl-derivatives (i)PrEl[Me2C2B9H9] (3, El = P; 4, El = As). 3 can also be obtained in low yields from the reaction of Li2[Me2C2B9H9] with (i)PrPCl2. 1 and 2 react with AlCl3 to give the adducts ClEl[Me2C2B9H9].AlCl3 (5, El = P; 6, El = As). Treatment of 1 with AgBF4 gives, under elimination of AgCl and BF3, the fluorinated analogon FP[Me2C2B9H9] (7). Comparison of the bonding situation in 1-7 with that in known isoelectronic cage-compounds of group 14 elements suggests a distorted icosahedral structure for 1-7, which has been proved in the case of 2 by an X-ray diffraction study.
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Jutzi P, WEGENER D, HURSTHOUSE M. SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1991;418(3):277-289.
Jutzi, P., WEGENER, D., & HURSTHOUSE, M. (1991). SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 418(3), 277-289.
Jutzi, P., WEGENER, D., and HURSTHOUSE, M. (1991). SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]. JOURNAL OF ORGANOMETALLIC CHEMISTRY 418, 277-289.
Jutzi, P., WEGENER, D., & HURSTHOUSE, M., 1991. SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 418(3), p 277-289.
P. Jutzi, D. WEGENER, and M. HURSTHOUSE, “SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]”, JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 418, 1991, pp. 277-289.
Jutzi, P., WEGENER, D., HURSTHOUSE, M.: SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 418, 277-289 (1991).
Jutzi, Peter, WEGENER, D, and HURSTHOUSE, M. “SYNTHESIS OF DICARBOLLYL COMPLEXES OF THE ELEMENTS PHOSPHORUS AND ARSENIC - X-RAY STRUCTURAL-ANALYSIS OF CLAS[C2ME2B9H9]”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 418.3 (1991): 277-289.
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