(NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY

Müller A, Krickemeyer E, Wittneben V, Bögge H, Lemke M (1991)
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 30(11): 1512-1514.

Journal Article | Published | English

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Abstract
A strong transannular Re-Re interaction and reactive metal-sulfur bonds characterize the title anion 1 (shown on the right without the two chelating S4-ligands). This surprising result explained by the existence of molecular orbitials arising from Re 5d and S 3p functions of similar energy are not only Re-Re bonding but also markedly delocalized. These findings underline the importance of the role of the metal center, especially in catalytically active metal sulfides.
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Müller A, Krickemeyer E, Wittneben V, Bögge H, Lemke M. (NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH. 1991;30(11):1512-1514.
Müller, A., Krickemeyer, E., Wittneben, V., Bögge, H., & Lemke, M. (1991). (NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 30(11), 1512-1514.
Müller, A., Krickemeyer, E., Wittneben, V., Bögge, H., and Lemke, M. (1991). (NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 30, 1512-1514.
Müller, A., et al., 1991. (NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 30(11), p 1512-1514.
A. Müller, et al., “(NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY”, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, vol. 30, 1991, pp. 1512-1514.
Müller, A., Krickemeyer, E., Wittneben, V., Bögge, H., Lemke, M.: (NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH. 30, 1512-1514 (1991).
Müller, Achim, Krickemeyer, Erich, Wittneben, V, Bögge, Hartmut, and Lemke, M. “(NH4)2[RE2S16], A SOLUBLE METAL SULFIDE WITH INTERESTING ELECTRONIC-PROPERTIES AND UNUSUAL REACTIVITY”. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH 30.11 (1991): 1512-1514.
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