NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2)

MOTTNER P, LERF A, BUTZ T, KNOZINGER H, Müller A, WITTNEBEN V, Krickemeyer E (1992)
CHEMICAL PHYSICS 160(2): 327-339.

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Abstract
The nuclear quadrupole interaction (NQI) of Mo-99(beta-)Tc-99 was measured by time differential perturbed angular correlations (TDPAC) in the following Mo-S-cluster compounds and ions: (NH4)2 [Mo3IVS(S2)6].nH2O (n = 0-2), [Mo3IVSS3(CN)9]5-, (NH4)2[Mo2V(S2)6].2H2O and [Mo2IIIS2(CN)8]6-. All compounds exhibit low NQIs with the exception of (NH4)2-[Mo3IVS(S2)6].nH2O which shows in addition to the low NQI a large fraction of a high NQI, possibly a consequence of the nuclear transmutation. In addition, we studied the thermal decomposition products of the [Mo3S(S2)6]2- cluster towards MoS2.15, which may serve as a model for technical hydrodesulfurization catalysts.
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MOTTNER P, LERF A, BUTZ T, et al. NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2). CHEMICAL PHYSICS. 1992;160(2):327-339.
MOTTNER, P., LERF, A., BUTZ, T., KNOZINGER, H., Müller, A., WITTNEBEN, V., & Krickemeyer, E. (1992). NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2). CHEMICAL PHYSICS, 160(2), 327-339.
MOTTNER, P., LERF, A., BUTZ, T., KNOZINGER, H., Müller, A., WITTNEBEN, V., and Krickemeyer, E. (1992). NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2). CHEMICAL PHYSICS 160, 327-339.
MOTTNER, P., et al., 1992. NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2). CHEMICAL PHYSICS, 160(2), p 327-339.
P. MOTTNER, et al., “NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2)”, CHEMICAL PHYSICS, vol. 160, 1992, pp. 327-339.
MOTTNER, P., LERF, A., BUTZ, T., KNOZINGER, H., Müller, A., WITTNEBEN, V., Krickemeyer, E.: NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2). CHEMICAL PHYSICS. 160, 327-339 (1992).
MOTTNER, P, LERF, A, BUTZ, T, KNOZINGER, H, Müller, Achim, WITTNEBEN, V, and Krickemeyer, Erich. “NUCLEAR-QUADRUPOLE INTERACTION OF MO-99(BETA-)TC-99 IN VARIOUS MOLYBDENUM SULFUR CLUSTER COMPOUNDS AND THERMAL-DECOMPOSITION PRODUCTS OF (NH4)2[MO3S(S2)6].NH2O (N=0-2)”. CHEMICAL PHYSICS 160.2 (1992): 327-339.
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