MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY

DETSCH R, NIECKE E, NIEGER M, Schoeller W (1992)
CHEMISCHE BERICHTE-RECUEIL 125(5): 1119-1124.

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Abstract
Metallation of the NH-functional amino(imino)phosphanes Mes*NPNHR (R = CPh3, Ad, tBu) 1a-c yields the 1,3-diaza-2-phosphaallyllithium compounds 2a-c. The crystal structure shows an ether-stabilized monomer of 2a and a solvent-free dimer with an eight-membered ring in the case of 2b,c. The reaction of 2b with chlorodiphenylphosphane yields, dependent on the reaction conditions, (phosphanylamino)iminophosphane 3 or bis(imino)phosphanylphosphorane 4. The structural and reactivity is discussed on the basis of ab initio calculations.
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DETSCH R, NIECKE E, NIEGER M, Schoeller W. MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY. CHEMISCHE BERICHTE-RECUEIL. 1992;125(5):1119-1124.
DETSCH, R., NIECKE, E., NIEGER, M., & Schoeller, W. (1992). MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY. CHEMISCHE BERICHTE-RECUEIL, 125(5), 1119-1124.
DETSCH, R., NIECKE, E., NIEGER, M., and Schoeller, W. (1992). MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY. CHEMISCHE BERICHTE-RECUEIL 125, 1119-1124.
DETSCH, R., et al., 1992. MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY. CHEMISCHE BERICHTE-RECUEIL, 125(5), p 1119-1124.
R. DETSCH, et al., “MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY”, CHEMISCHE BERICHTE-RECUEIL, vol. 125, 1992, pp. 1119-1124.
DETSCH, R., NIECKE, E., NIEGER, M., Schoeller, W.: MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY. CHEMISCHE BERICHTE-RECUEIL. 125, 1119-1124 (1992).
DETSCH, R, NIECKE, E, NIEGER, M, and Schoeller, Wolfgang. “MONOMER AND DIMER 1,3-DIAZA-2-PHOSPHAALLYLLITHIUM COMPLEXES - STRUCTURES AND AMBIDENT REACTIVITY”. CHEMISCHE BERICHTE-RECUEIL 125.5 (1992): 1119-1124.
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