NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES

Jutzi P, OPIELA S (1992)
JOURNAL OF ORGANOMETALLIC CHEMISTRY 431(2): C29-C32.

Journal Article | Published | English

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Abstract
In the reaction with nucleophiles of the type M'[M(CO)2C5R5] (M' = Na, K; M = Fe. Ru: R = H. CH3), the pentamethylcyclopentadienyl (Cp*) ligand in the known diphosphenes Cp*P=PMes* and Cp*P=PCp*, and in the arsaphosphene Cp*As=PMes* acts as a nucleofugal leaving group. This behaviour opens an alternative synthetic route to transition-metal substituted diphosphenes, arsaphosphenes, and tetraphospha-bicyclobutanes.
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Jutzi P, OPIELA S. NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1992;431(2):C29-C32.
Jutzi, P., & OPIELA, S. (1992). NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 431(2), C29-C32.
Jutzi, P., and OPIELA, S. (1992). NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES. JOURNAL OF ORGANOMETALLIC CHEMISTRY 431, C29-C32.
Jutzi, P., & OPIELA, S., 1992. NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 431(2), p C29-C32.
P. Jutzi and S. OPIELA, “NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES”, JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 431, 1992, pp. C29-C32.
Jutzi, P., OPIELA, S.: NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 431, C29-C32 (1992).
Jutzi, Peter, and OPIELA, S. “NEW PREPARATION METHOD FOR METAL-FUNCTIONALIZED DIPHOSPHENES, ARSAPHOSPHENES AND TETRAPHOSPHABICYCLOBUTANES”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 431.2 (1992): C29-C32.
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