(DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN)

Jutzi P, DAHLHAUS J, BANGEL M (1993)
JOURNAL OF ORGANOMETALLIC CHEMISTRY 460(2): C13-C15.

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Abstract
The synthesis of cyclopentadienyl complexes containing polydentate C(5)R(4)(CH(2)CH(2)NMe(2)) ligands (R = H, Me) and Group 13 elements (Al, Ga, In) is described. The compounds (C(5)Me(4)CH(2)CH(2)NMe(2)) AIX(2) (X = Me, Cl, Br, I), (C(5)Me(4)CH(2)CH(2)NMe(2))MCl(2), (M = Ga, In), (C(5)H(4)CH(2)CH(2)NMe(2))AIX(2) (X = H, Me, Et, Cl), (C5H4CH2- CH(2)NMe(2))GaCl2, and (C(5)H(4)CH(2)CH(2)NMe(2))InMe(2) are obtained by three different procedures. All compounds that have been characterized, so far, by X-ray diffraction studies show an additional intramolecular coordination of the nitrogen atom in the side chain. Monomeric structures and sufficient volatilities make them potential candidates for MOCVD processes.
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Jutzi P, DAHLHAUS J, BANGEL M. (DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN). JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1993;460(2):C13-C15.
Jutzi, P., DAHLHAUS, J., & BANGEL, M. (1993). (DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 460(2), C13-C15.
Jutzi, P., DAHLHAUS, J., and BANGEL, M. (1993). (DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN). JOURNAL OF ORGANOMETALLIC CHEMISTRY 460, C13-C15.
Jutzi, P., DAHLHAUS, J., & BANGEL, M., 1993. (DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN). JOURNAL OF ORGANOMETALLIC CHEMISTRY, 460(2), p C13-C15.
P. Jutzi, J. DAHLHAUS, and M. BANGEL, “(DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN)”, JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 460, 1993, pp. C13-C15.
Jutzi, P., DAHLHAUS, J., BANGEL, M.: (DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN). JOURNAL OF ORGANOMETALLIC CHEMISTRY. 460, C13-C15 (1993).
Jutzi, Peter, DAHLHAUS, J, and BANGEL, M. “(DIMETHYLAMINOETHYL)CYCLOPENTADIENYL LIGANDS IN THE CHEMISTRY OF GROUP-13 ELEMENTS (AL, GA, IN)”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 460.2 (1993): C13-C15.
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