MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O

Müller A, Rohlfing R, Barra AL, Gatteschi D (1993)
ADVANCED MATERIALS 5(12): 915-917.

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Abstract
Oxovanadium clusters are interesting both as models of bulk magnets and in their own right. Results are presented suggesting that in Na-6[H6V12O30F2].22H(2)O (see Figure) it is meaningful to decide which particular vanadium centers should be considered as 5+ and which as 4+. It is shown that in principle it is possible to tune and design the topology, and thus the magnetic properties, of polyoxovanadates(IV/V) by means of the template effect.
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Müller A, Rohlfing R, Barra AL, Gatteschi D. MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O. ADVANCED MATERIALS. 1993;5(12):915-917.
Müller, A., Rohlfing, R., Barra, A. L., & Gatteschi, D. (1993). MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O. ADVANCED MATERIALS, 5(12), 915-917.
Müller, A., Rohlfing, R., Barra, A. L., and Gatteschi, D. (1993). MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O. ADVANCED MATERIALS 5, 915-917.
Müller, A., et al., 1993. MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O. ADVANCED MATERIALS, 5(12), p 915-917.
A. Müller, et al., “MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O”, ADVANCED MATERIALS, vol. 5, 1993, pp. 915-917.
Müller, A., Rohlfing, R., Barra, A.L., Gatteschi, D.: MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O. ADVANCED MATERIALS. 5, 915-917 (1993).
Müller, Achim, Rohlfing, Ralf, Barra, A. L., and Gatteschi, D. “MAGNETIC-PROPERTIES OF POLYOXOVANADATES - MAGNETIC CONFIRMATION OF THE VALENCE STATE OF THE VANADIUM CENTERS IN NA-6[H6V12O30F2]CENTER-DOT-22H(2)O”. ADVANCED MATERIALS 5.12 (1993): 915-917.
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