(SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES

Jutzi P, LEUE C (1994)
ORGANOMETALLICS 13(7): 2898-2899.

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Abstract
GeCl2.(dioxane) (1) reacts at low temperatures with stoichiometric amounts of (2,4,6-tri-tert-butylphenyl)lithium to give the unsymmetrically substituted (supermesityl)chlorogermylene (2), which is stable at ambient temperature. The monomeric structure of 2 has been proven both in solution and in the solid state. 2 is a suitable substrate for the synthesis of mixed germylenes. Thus, reaction of 2 with Cp*Li leads to the germylene Mes*GeCp* (3), whereas the reaction with the corresponding alkali-metal metalates yields the first organometallogermylenes, Mes*GeFe(CO)2R (4, R = Cp*; 5, R = Cp).
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Jutzi P, LEUE C. (SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES. ORGANOMETALLICS. 1994;13(7):2898-2899.
Jutzi, P., & LEUE, C. (1994). (SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES. ORGANOMETALLICS, 13(7), 2898-2899.
Jutzi, P., and LEUE, C. (1994). (SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES. ORGANOMETALLICS 13, 2898-2899.
Jutzi, P., & LEUE, C., 1994. (SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES. ORGANOMETALLICS, 13(7), p 2898-2899.
P. Jutzi and C. LEUE, “(SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES”, ORGANOMETALLICS, vol. 13, 1994, pp. 2898-2899.
Jutzi, P., LEUE, C.: (SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES. ORGANOMETALLICS. 13, 2898-2899 (1994).
Jutzi, Peter, and LEUE, C. “(SUPERMESITYL)CHLOROGERMYLENE (SUPERMESITYL = TBU3C6H2) - SYNTHESIS AND DERIVATIZATION TO (SUPERMESITYL)FERRIOGERMYLENES”. ORGANOMETALLICS 13.7 (1994): 2898-2899.
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