CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS

Jutzi P, BRUSDEILINS N (1994)
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 620(8): 1375-1380.

Journal Article | Published | English

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Abstract
The thermolysis of 1,2,3-tris(pentamethylcyclopentadienyl) cyclotriphosphane [(Cp*P)3, 1] or 2,3,4,6-Tetrakis(pentamethylcyclopentadienyl) bicyclo[3.1.0]hexaphosphane [Cp4*P6, 2] leads in addition to the known 3,4-bis(pentamethylcyclopentadienyl) tricyclo[3.1.0.0(2,6)]hexaphosphane [Cp2*P6, 3] to the pentacyclic carbaphosphanes 3,4,5,6,11-pentamethyl-endo-9-pentamethylcyclopentadienyl-3, 4,5,6,11-pentacarba-pentacyclo [6.1.1(1,8).1(3,6).0(2,7)0(10,11)]-4-en-undecaphosphane and 3,4,5,6, 11-pentamethyl-exo-9-pentamethylcyclopentadienyl-3,4,5,6,11-pentacarba-p entacyclo [6.1.1(1,80.1(3.6).0(2,7)0(10,11)]-4-en-undecaphosphane [Cp*Me5P6C5, 4a, 4b]. Furthermore, other polyphosphanes are formed, like 1,2,3,4-tetrakis(pentamethylcyclopentadienyl) cyclotetraphosphane [(Cp*P)4, 5] and 2,4-bis(pentamethylcyclopentadienyl)-tetraphosphabicyclo [1.1.0]butane [(Cp*P)2P2, 6]. The structure of 4a and 4b is determined by NMR-spectroscopy. The molecule contains a P5C3-cunean-unit, to which a C2Me2-brigde and a PCp*-brigde is bonded.
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Jutzi P, BRUSDEILINS N. CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 1994;620(8):1375-1380.
Jutzi, P., & BRUSDEILINS, N. (1994). CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 620(8), 1375-1380.
Jutzi, P., and BRUSDEILINS, N. (1994). CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 620, 1375-1380.
Jutzi, P., & BRUSDEILINS, N., 1994. CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 620(8), p 1375-1380.
P. Jutzi and N. BRUSDEILINS, “CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS”, ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, vol. 620, 1994, pp. 1375-1380.
Jutzi, P., BRUSDEILINS, N.: CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE. 620, 1375-1380 (1994).
Jutzi, Peter, and BRUSDEILINS, N. “CP(ASTERISK)ME5P6C5 - A NEW CARBAPHOSPHANE WITH A STRUCTURE UNIT OF HITTORF-PHOSPHORUS”. ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE 620.8 (1994): 1375-1380.
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