THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL

Jutzi P, SCHMIDT H, NEUMANN B, Stammler H-G (1995)
JOURNAL OF ORGANOMETALLIC CHEMISTRY 499(1-2): 7-10.

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Abstract
1-(Dimethylaminoethyl)-2,3,4,5-tetramethylcyclopentadienyl(chloro)germy (1) is prepared from GeCl2 . dioxane and 1-(dimethylaminoethyl)-2,3,4,5-cyclopentadienyllithium. In 1 the nitrogen atom of the side chain is coordinated to the Ge(II) center. As a consequence of N coordination, the Ge-Cl bond is one of the longest ever found, and the Ge-Cp interaction is in between pi and sigma bonding.
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Jutzi P, SCHMIDT H, NEUMANN B, Stammler H-G. THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1995;499(1-2):7-10.
Jutzi, P., SCHMIDT, H., NEUMANN, B., & Stammler, H. - G. (1995). THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 499(1-2), 7-10.
Jutzi, P., SCHMIDT, H., NEUMANN, B., and Stammler, H. - G. (1995). THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL. JOURNAL OF ORGANOMETALLIC CHEMISTRY 499, 7-10.
Jutzi, P., et al., 1995. THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 499(1-2), p 7-10.
P. Jutzi, et al., “THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL”, JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 499, 1995, pp. 7-10.
Jutzi, P., SCHMIDT, H., NEUMANN, B., Stammler, H.-G.: THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 499, 7-10 (1995).
Jutzi, Peter, SCHMIDT, H, NEUMANN, B, and Stammler, Hans-Georg. “THE DIMETHYLAMINOETHYL-TETRAMETHYLCYCLOPENTADIENYL LIGAND IN GERMANIUM(II) CHEMISTRY - SYNTHESIS, PROPERTIES AND X-RAY CRYSTAL STRUCTURAL DATA OF (ME(2)NCH(2)CH(2))ME(4)C(5)GECL”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 499.1-2 (1995): 7-10.
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