SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS

Jutzi P, WIELAND W, NEUMANN B, Stammler H-G (1995)
JOURNAL OF ORGANOMETALLIC CHEMISTRY 501(1-2): 369-374.

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Abstract
Copper is the only element in the 3d series from which no dicyclopentadienyl compounds are known to date. Starting from cyclopentadienyllithium and copper(I) chloride, two novel organocuprates, [PPh(4)][CuCp(2)] (1) and [Li(12-crown-4)(2)][Cu(2)Cp(3)]. 2THF (2), were prepared. The solid-state structural features in the anions of 1 and 2 are hitherto unknown; eta(2)-Cp coordination to the copper centres is observed by X-ray analysis. NMR spectroscopic analyses confirm the pronounced molecular dynamics in solution. Compounds of the general-formula LiCu(C(5)R(5))(2) are powerful Cp-transfer reagents.
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Jutzi P, WIELAND W, NEUMANN B, Stammler H-G. SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1995;501(1-2):369-374.
Jutzi, P., WIELAND, W., NEUMANN, B., & Stammler, H. - G. (1995). SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 501(1-2), 369-374.
Jutzi, P., WIELAND, W., NEUMANN, B., and Stammler, H. - G. (1995). SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS. JOURNAL OF ORGANOMETALLIC CHEMISTRY 501, 369-374.
Jutzi, P., et al., 1995. SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 501(1-2), p 369-374.
P. Jutzi, et al., “SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS”, JOURNAL OF ORGANOMETALLIC CHEMISTRY, vol. 501, 1995, pp. 369-374.
Jutzi, P., WIELAND, W., NEUMANN, B., Stammler, H.-G.: SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 501, 369-374 (1995).
Jutzi, Peter, WIELAND, W, NEUMANN, B, and Stammler, Hans-Georg. “SLIPPED SANDWICH STRUCTURES IN THE CHEMISTRY OF CYCLOPENTADIENYL COPPER-COMPOUNDS”. JOURNAL OF ORGANOMETALLIC CHEMISTRY 501.1-2 (1995): 369-374.
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